1 Ocak 2015 Dergi makalesi Açık Erişim

Karadag, Ahmet; Aydin, Ali; Dede, Sureyya; Tekin, Saban; Yanar, Yusuf; Cadirci, Bilge Hilal; Soylu, Mustafa Serkan; Andac, Omer

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  "@id": 80513, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Gaziosmanpasa Univ, Coll Art & Sci, Dept Chem, TR-60240 Tokat, Turkey", 
      "name": "Karadag, Ahmet"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gaziosmanpasa Univ, Dept Mol Biol & Genet, TR-60240 Tokat, Turkey", 
      "name": "Aydin, Ali"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gaziosmanpasa Univ, Coll Art & Sci, Dept Chem, TR-60240 Tokat, Turkey", 
      "name": "Dede, Sureyya"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gaziosmanpasa Univ, Dept Mol Biol & Genet, TR-60240 Tokat, Turkey", 
      "name": "Tekin, Saban"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gaziosmanpasa Univ, Fac Agr, Dept Plant Protect, TR-60240 Tokat, Turkey", 
      "name": "Yanar, Yusuf"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gaziosmanpasa Univ, Engn & Nat Sci Fac, Dept Bioengn, TR-60240 Tokat, Turkey", 
      "name": "Cadirci, Bilge Hilal"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Giresun Univ, Fac Art & Sci, Dept Phys, TR-28100 Giresun, Turkey", 
      "name": "Soylu, Mustafa Serkan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ondokuz Mayis Univ, Coll Art & Sci, Dept Chem, TR-55139 Samsun, Turkey", 
      "name": "Andac, Omer"
    }
  ], 
  "datePublished": "2015-01-01", 
  "description": "Five new cyanido-bridged coordination polymers having closed formulae [Ni(hydeten)Au-2(CN)(4)] (C1), [Ni(hydeten)(2)Au-2(CN)(4)]center dot H2O (C2), [Cu(hydeten)(2)Au-2(CN)(4)]center dot CH3OH (C3), [Zn(hydeten)(2) Au-2(CN)(4)]center dot H2O (C4), and [Cd(hydeten)(2)Au-2(CN)(4)]center dot H2O (C5) (hydeten: N-(2-hydroxyethyl)-ethylenediamine) have been prepared and characterized by elemental, thermal, FT-IR and XRD (C3, C4 and C5) measurement techniques. The anticancer, antibacterial and antifungal activities of the complexes are also investigated. The C3, C4 and C5 units according to XRD analyses are linked to each other via -CN-M(hydeten)-NC-Au(1)-CN-M(hydeten)-CN- chains (M-II = Cu, Zn and Cd) and aurophilic interacted -Au(1)(CN)2-Au(2)(CN)2-Au(1)(CN)2-Au(2)(CN)2- zig-zag shaped chains along the a axis. C1, C2 and C4 show significant antifungal effects against several plant pathogenic fungi, while surprisingly C3 exhibits a considerable antibacterial effect against Gram negative E. coli. The studies of the antiproliferative activity on Hela, HT29 and C6 tumor cell lines indicated the anticancer potential of these complexes even at low doses.", 
  "headline": "Five novel dicyanidoaurate(I)-based complexes exhibiting significant biological activities: synthesis, characterization and three crystal structures", 
  "identifier": 80513, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Five novel dicyanidoaurate(I)-based complexes exhibiting significant biological activities: synthesis, characterization and three crystal structures", 
  "url": "https://aperta.ulakbim.gov.tr/record/80513"
}