Dergi makalesi Açık Erişim
Emirdag-Eanes, Mehtap; Onen, Banu; McMillen, Colin D.
{ "conceptrecid": "80124", "created": "2021-03-16T05:29:44.046983+00:00", "doi": "10.1016/j.ica.2014.12.018", "files": [ { "bucket": "3eec6a2a-0c16-4e17-aa09-d47c5c7cdd63", "checksum": "md5:7ad07db2001b7878262ae30784b3151e", "key": "bib-c11fa1a7-0484-41db-87c8-027502190ea0.txt", "links": { "self": "https://aperta.ulakbim.gov.tr/api/files/3eec6a2a-0c16-4e17-aa09-d47c5c7cdd63/bib-c11fa1a7-0484-41db-87c8-027502190ea0.txt" }, "size": 237, "type": "txt" } ], "id": 80125, "links": { "badge": "https://aperta.ulakbim.gov.tr/badge/doi/10.1016/j.ica.2014.12.018.svg", "bucket": "https://aperta.ulakbim.gov.tr/api/files/3eec6a2a-0c16-4e17-aa09-d47c5c7cdd63", "doi": "https://doi.org/10.1016/j.ica.2014.12.018", "html": "https://aperta.ulakbim.gov.tr/record/80125", "latest": "https://aperta.ulakbim.gov.tr/api/records/80125", "latest_html": "https://aperta.ulakbim.gov.tr/record/80125" }, "metadata": { "access_right": "open", "access_right_category": "success", "communities": [ { "id": "tubitak-destekli-proje-yayinlari" } ], "creators": [ { "affiliation": "Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkey", "name": "Emirdag-Eanes, Mehtap" }, { "affiliation": "Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkey", "name": "Onen, Banu" }, { "affiliation": "Clemson Univ, Dept Chem, Clemson, SC 29634 USA", "name": "McMillen, Colin D." } ], "description": "Two novel polymeric polyoxometallates constructed from transition metal substituted heteropolytung-states, [(4,4'bpyH(2))(2)(4,4'bpyH)][PCuW11O39]center dot H2O (1), and [(4,4'bpyH(2))(pyH)(3)][PCuW11O39]center dot 2H(2)O (2), (4,4'bpy = 4,4'bipyridine, py = pyridine) have been synthesized under hydrothermal conditions and characterized by IR, TGA, single crystal X-ray diffraction and magnetic measurements. The product formation showed a high sensitivity toward experimental factors including pH and stirring. Compounds 1 crystallizes in the monoclinic space group P2(1)/n with a = 13.503(3) angstrom , b = 26.726(5) angstrom, c = 15.168(3) angstrom, beta = 99.61(3)degrees and Z = 4. The second compound also crystallizes in space group P2(1)/n, but with a = 13.519(3) angstrom, b = 20.431(4) angstrom, c = 18.655(4) angstrom, beta = 96.52(3)degrees and Z = 4. Compound 1 exhibits a zigzag chain structure, while compound 2 exhibits a straight chain structure. Compound 2 is the first example of a polyoxometallate containing 1D chains of transition-metal-substituted heteropolytungstate designed with two significantly different organic units as the countercations. The Cu2+ ions in 1 exhibit paramagnetic behavior. (C) 2015 Elsevier B.V. All rights reserved.", "doi": "10.1016/j.ica.2014.12.018", "has_grant": false, "journal": { "pages": "219-225", "title": "INORGANICA CHIMICA ACTA", "volume": "427" }, "license": { "id": "cc-by" }, "publication_date": "2015-01-01", "relations": { "version": [ { "count": 1, "index": 0, "is_last": true, "last_child": { "pid_type": "recid", "pid_value": "80125" }, "parent": { "pid_type": "recid", "pid_value": "80124" } } ] }, "resource_type": { "subtype": "article", "title": "Dergi makalesi", "type": "publication" }, "title": "Hydrothermal synthesis and characterization of one dimensional chain structures of monolacunary Keggin polyoxoanions substituted with copper" }, "owners": [ 1 ], "revision": 1, "stats": { "downloads": 9.0, "unique_downloads": 9.0, "unique_views": 32.0, "version_downloads": 9.0, "version_unique_downloads": 9.0, "version_unique_views": 32.0, "version_views": 35.0, "version_volume": 2133.0, "views": 35.0, "volume": 2133.0 }, "updated": "2021-03-16T05:29:44.107985+00:00" }
Görüntülenme | 35 |
İndirme | 9 |
Veri hacmi | 2.1 kB |
Tekil görüntülenme | 32 |
Tekil indirme | 9 |