1 Ocak 2020 Dergi makalesi Açık Erişim

Samav, Yasemin; Akpinar, Bernice; Kocak, Gokhan; Butun, Vural

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/7895</identifier>
  <creators>
    <creator>
      <creatorName>Samav, Yasemin</creatorName>
      <givenName>Yasemin</givenName>
      <familyName>Samav</familyName>
    </creator>
    <creator>
      <creatorName>Akpinar, Bernice</creatorName>
      <givenName>Bernice</givenName>
      <familyName>Akpinar</familyName>
      <affiliation>Eskisehir Osmangazi Univ, Dept Chem, Facullty Sci &amp; Letters, TR-26040 Eskisehir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kocak, Gokhan</creatorName>
      <givenName>Gokhan</givenName>
      <familyName>Kocak</familyName>
      <affiliation>Adiyaman Univ, Vocat Sch Higher Educ, Dept Chem &amp; Chem Proc Technol, TR-02040 Adiyaman, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Butun, Vural</creatorName>
      <givenName>Vural</givenName>
      <familyName>Butun</familyName>
      <affiliation>Eskisehir Osmangazi Univ, Dept Chem, Facullty Sci &amp; Letters, TR-26040 Eskisehir, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Preparation Of Responsive Zwitterionic Diblock Copolymers Containing Phosphate And Phosphonate Groups</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/7895</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1007/s13233-020-8148-3</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this study, novel zwitterionic diblock copolymers, namely poly(2-(N-morpholino)ethyl methacrylate))-block-poly(2-(methacryloyloxy)ethyl phosphate) (PMEMA-b-PMOEP) and poly(2-(N-morpholino)ethyl methacrylate))-block-poly ((methacryloyloxy)methyl phosphonic acid) (PMEMA-b-PMOMP), were synthesizedviareversible addition-fragmentation chain transfer controlled radical polymerization. Solution properties of these phosphorus-based diblock copolymers were investigated using dynamic light scattering, transmission electron microscopy and proton nuclear magnetic resonance spectroscopy. Since the PMEMA block has both salt- and thermo-responsive properties, PMEMA-b-PMOEP and PMEMA-b-PMOMP diblock copolymers formed core-shell micelles in basic aqueous media as the PMEMA block formed insoluble micelle core with the addition of Na2SO4 or an increase in temperature in basic solution. Additionally, PMEMA-b-PMOMP diblock copolymers interacted strongly with calcium cations and yielded reverse micellar structures via complexation of phosphate with metal cation in aqueous media.</description>
  </descriptions>
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