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Electrochemical and optical studies of two synthesized cobalt complexes as anti-corrosion agent for low-carbon steel in HCl medium

Keles, Hulya; Keles, Mustafa


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        "affiliation": "Osmaniye Korkut Ata Univ, Dept Chem, Fac Arts & Sci, TR-80000 Osmaniye, Turkey", 
        "name": "Keles, Hulya"
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      {
        "affiliation": "Osmaniye Korkut Ata Univ, Dept Chem, Fac Arts & Sci, TR-80000 Osmaniye, Turkey", 
        "name": "Keles, Mustafa"
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    "description": "Two novel synthesized Co(II) complexes, named diacetato(1-(2-methoxyphenyl)-N-(2-(phenylthio)phenyl)methanimine)cobalt(II) (CoMPM) and diacetato(2-(phenylthio)phenyl)-1-(2-(trifluoromethyl)phenyl)methanimine)cobalt(II) (CoPFM), have been investigated as an anti-corrosion agent for low-carbon steel in 1.0M HCl solution. The protection performance of Co(II) complexes was evaluated using electrochemical and optical methods. The inhibition efficiency was investigated as a function of exposure time, inhibitor concentration, and different potentiostatic potentials. CoPFM (99.4%) was found more efficient as a corrosion inhibitor in negative potentiostatic polarization conditions than CoMPM (98.4%). However, CoMPM (99.2%) showed a better protection when it was compared to CoPFM (95.7%) at the end of 120-h immersion.", 
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      "pages": "871-885", 
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    "publication_date": "2019-01-01", 
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