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Fatty acid alkyl ester nanowebs suitable for renewable thermal energy storage

Onder, Emel; Sarier, Nihal


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{
  "DOI": "10.1016/j.tca.2020.178698", 
  "abstract": "Owing to their high heat absorption and release capacities, chemical and thermal stability, non-toxicity, two fatty acid alkyl esters (FAAEs), methyl palmitate (MP) and isopropyl palmitate (IPP), were investigated for their use as thermal energy storage (TES) material in a shape stabilized form. Four nanowebs were developed via coaxial electrospinning, using poly(acrylo nitrile) (PAN) or poly(methacrylic acid-co-ethyl acrylate) (PMEA) shell to envelope MP or IPP core. Scanning electron microscope (SEM), transmission electron microscope (TEM) images confirmed cylindrical nanofiber formation, demonstrating a coaxial sheath-core morphology. The phase change enthalpies of PAN-MP, PMEA-MP nanowebs, with average diameters of 259-289 nm, were 71 J g(-1) and 86 J g(-1) at 28-32 degrees C, and those of PAN-IPP, PMAE-IPP were 72 J g(-1) and 60 J g(-1) at 7-15 degrees C during heating cycle in differential scanning calorimeter (DSC) analyses. A composite including PAN-MP nanoweb performed enhanced thermo-physical properties than its control counterpart.", 
  "author": [
    {
      "family": "Onder", 
      "given": " Emel"
    }, 
    {
      "family": "Sarier", 
      "given": " Nihal"
    }
  ], 
  "container_title": "THERMOCHIMICA ACTA", 
  "id": "7335", 
  "issued": {
    "date-parts": [
      [
        2020, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Fatty acid alkyl ester nanowebs suitable for renewable thermal energy storage", 
  "type": "article-journal", 
  "volume": "690"
}
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