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Development of thermo-regulating fabrics using PCM microcapsules with poly(methyl methacrylate-co-2-hydroxy ethyl methacrylate) shell and n-alkane core

Altun-Anayurt, Ruhan; Alay-Aksoy, Sennur; Alkan, Cemil; Demirbag, Sena; Tozum, M. Selda


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{
  "@context": "https://schema.org/", 
  "@id": 69857, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Cankiri Karatekin Univ, Dept Occupat Hlth & Safety, Cankiri, Turkey", 
      "name": "Altun-Anayurt, Ruhan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Suleyman Demirel Univ, Dept Text Engn, Isparta, Turkey", 
      "name": "Alay-Aksoy, Sennur"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gaziosmanpasa Univ, Dept Chem, Tokat, Turkey", 
      "name": "Alkan, Cemil"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Usak Univ, Dept Text Engn, Usak, Turkey", 
      "name": "Demirbag, Sena"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Usak Univ, Dept Text Engn, Usak, Turkey", 
      "name": "Tozum, M. Selda"
    }
  ], 
  "datePublished": "2019-01-01", 
  "description": "Purpose The purpose of this paper is to prepare microencapsulated phase change materials (PCMs) and apply them to cotton and wool fabrics for developing thermo-regulating fabrics. Design/methodology/approach Microencapsulated n-hexadecane and n-octadecane with poly(methylmethacrylate-co-2-hydroxy ethyl methacrylate) shell was prepared. Microcapsules were fabricated using oil-in-water emulsion polymerization method. Their chemical structure, microstructure, thermal energy storage properties and thermal stability were analyzed by Fourier-transform infrared spectroscopy, polarized light microscope, differential scanning calorimeter and thermogravimetric analyzer, respectively. The mean particle size was tested by a particle sized instrument. The microcapsules were applied to the wool and cotton fabrics using pad-dry-cure method. The thermo-regulating property of the fabrics was evaluated using the T-History test. The distribution and durability of the microcapsules on the fabrics was investigated with scanning electron microscopy. Findings Spherical microcapsules with p(MMA-co-HEMA) shell and n-alkane core have been produced successfully. n-hexadecane in microcapsule solidifies at 14.8-15.6 degrees C with the latent heat of 65.6-129.8 J/g and melts at 16.7-16.9 degrees C with the latent heat of 67.6-136.9 J/g. Microencapsulated n-octadecane solidifies at 25.8-26.3 degrees C with the latent heat of 74.1-106.2 J/g and melts at 26.8-27.4 degrees C with the latent heat of 80.3-113.4 J/g. The microcapsules have enough thermal stability to the temperature of 150 degrees C that was applied during the fixation of microcapsules on the fabric. The thermo-regulating effect of the microcapsule-incorporated fabrics has been proved by the T-history test. Originality/value PCM microcapsules with p(MMA-co-HEMA) shell and n-hexadecane and n-octadecane core have been produced and their usage to produce thermo-regulating textiles have been proved. To determine the thermo-regulating property of the fabrics treated with these new PCM microcapsules, a T-History system has been designed.", 
  "headline": "Development of thermo-regulating fabrics using PCM microcapsules with poly(methyl methacrylate-co-2-hydroxy ethyl methacrylate) shell and n-alkane core", 
  "identifier": 69857, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Development of thermo-regulating fabrics using PCM microcapsules with poly(methyl methacrylate-co-2-hydroxy ethyl methacrylate) shell and n-alkane core", 
  "url": "https://aperta.ulakbim.gov.tr/record/69857"
}
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