Dergi makalesi Açık Erişim
Ilyas, Hafsa; Shawuti, Shalima; Siddiq, Muhammad; Niazi, Javed H.; Qureshi, Anjum
{ "conceptrecid": "68298", "created": "2021-03-16T02:46:34.712376+00:00", "doi": "10.1016/j.colsurfa.2019.123646", "files": [ { "bucket": "81bcd1f2-8560-4e6d-be2c-475fa4eece0a", "checksum": "md5:d13e812472d4e2b7d14550ec8b70219b", "key": "bib-23bed25b-be2c-4060-be09-1fdb66543b53.txt", "links": { "self": "https://aperta.ulakbim.gov.tr/api/files/81bcd1f2-8560-4e6d-be2c-475fa4eece0a/bib-23bed25b-be2c-4060-be09-1fdb66543b53.txt" }, "size": 300, "type": "txt" } ], "id": 68299, "links": { "badge": "https://aperta.ulakbim.gov.tr/badge/doi/10.1016/j.colsurfa.2019.123646.svg", "bucket": "https://aperta.ulakbim.gov.tr/api/files/81bcd1f2-8560-4e6d-be2c-475fa4eece0a", "doi": "https://doi.org/10.1016/j.colsurfa.2019.123646", "html": "https://aperta.ulakbim.gov.tr/record/68299", "latest": "https://aperta.ulakbim.gov.tr/api/records/68299", "latest_html": "https://aperta.ulakbim.gov.tr/record/68299" }, "metadata": { "access_right": "open", "access_right_category": "success", "communities": [ { "id": "tubitak-destekli-proje-yayinlari" } ], "creators": [ { "name": "Ilyas, Hafsa" }, { "affiliation": "Sabanci Univ, Fac Engn & Nat Sci, TR-34956 Istanbul, Turkey", "name": "Shawuti, Shalima" }, { "affiliation": "Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan", "name": "Siddiq, Muhammad" }, { "affiliation": "Sabanci Univ, SUNUM Nanotechnol Res & Applicat Ctr, TR-34956 Istanbul, Turkey", "name": "Niazi, Javed H." }, { "affiliation": "Sabanci Univ, SUNUM Nanotechnol Res & Applicat Ctr, TR-34956 Istanbul, Turkey", "name": "Qureshi, Anjum" } ], "description": "In this study, polyethylene glycol (PEG) functionalized graphene oxide-silver nanocomposite (PEG-GOAg) was used as an effective nano-additive to enhance the hydrophilicity, permeability and antifouling resistance of poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP) support membrane. PEG-GOAg was synthesized by in-situ reduction of GO nanosheets with AgNO3 followed by covalent PEGylation reaction. PEG-GOAg active layer based PVDF-co-HFP membranes were then fabricated by resin infiltration method. Water contact angle of pristine membrane decreased effectively from 115.02 degrees to 38.77 degrees upon PEG-functionalization (1 PEG-GOAg-P). PEG-GOAg loading enhanced the hydrophilicity, permeability, porosity and antifouling properties of pristine membrane by up to 1 wt% due to intercalation of PEG chains on GOAg nanostructure. Water flux capacity of Pristine-P and GOAg-P membranes exhibited lower flux values with 216 and 564 Lm(-2) h(-1), respectively as compared with that of 1 PEG-GOAg-P membrane, which increased to 906 Lm(-2) h(-1). The 1 PEG-GOAg-P membrane also showed highest flux recovery ratio (91.3%) and BSA protein rejection rate (95.1%). Further, irreversible fouling ratio was lower with 1 PEG-GOAg-P (R-ir (similar to)8.6%) as compared with pristine (49.1%) and 1 GOAg-P (22.8%) membranes, which demonstrated the high water permeability performance of 1 PEG-GOAg-P membrane. The presented study offers a great potential to optimize quality and cost in fabrication of high-performance polymeric nanocomposite membranes for a wide range of industrial ultrafiltration applications.", "doi": "10.1016/j.colsurfa.2019.123646", "has_grant": false, "journal": { "title": "COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS", "volume": "579" }, "license": { "id": "cc-by" }, "publication_date": "2019-01-01", "relations": { "version": [ { "count": 1, "index": 0, "is_last": true, "last_child": { "pid_type": "recid", "pid_value": "68299" }, "parent": { "pid_type": "recid", "pid_value": "68298" } } ] }, "resource_type": { "subtype": "article", "title": "Dergi makalesi", "type": "publication" }, "title": "PEG functionalized graphene oxide-silver nano-additive for enhanced hydrophilicity, permeability and fouling resistance properties of PVDF-co-HFP membranes" }, "owners": [ 1 ], "revision": 1, "stats": { "downloads": 16.0, "unique_downloads": 16.0, "unique_views": 74.0, "version_downloads": 16.0, "version_unique_downloads": 16.0, "version_unique_views": 74.0, "version_views": 92.0, "version_volume": 4800.0, "views": 92.0, "volume": 4800.0 }, "updated": "2021-03-16T02:46:34.761115+00:00" }
Görüntülenme | 92 |
İndirme | 16 |
Veri hacmi | 4.8 kB |
Tekil görüntülenme | 74 |
Tekil indirme | 16 |