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Simultaneous Polymerization-Induced Self-Assembly (PISA) and Guest Molecule Encapsulation

Karagoz, Bunyamin; Boyer, Cyrille; Davis, Thomas P.


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/64867</identifier>
  <creators>
    <creator>
      <creatorName>Karagoz, Bunyamin</creatorName>
      <givenName>Bunyamin</givenName>
      <familyName>Karagoz</familyName>
    </creator>
    <creator>
      <creatorName>Boyer, Cyrille</creatorName>
      <givenName>Cyrille</givenName>
      <familyName>Boyer</familyName>
    </creator>
    <creator>
      <creatorName>Davis, Thomas P.</creatorName>
      <givenName>Thomas P.</givenName>
      <familyName>Davis</familyName>
    </creator>
  </creators>
  <titles>
    <title>Simultaneous Polymerization-Induced Self-Assembly (Pisa) And Guest Molecule Encapsulation</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2014</publicationYear>
  <dates>
    <date dateType="Issued">2014-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/64867</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/marc.201300730</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Nanoparticles with various morphologies such as micelles, worm-like/rod-like and spherical vesicles are made using a polymerization-induced self-assembly (PISA) approach via a one-pot RAFT dispersion polymerization. On polymerization/self-assembly, we report a concurrent highly efficient loading of guest molecules within the nanoparticle structures. Different nanoparticle morphologies, such as spherical micelles, worm-like, rod-like, and spherical vesicles, are achieved by gradually increasing the number-average degree of polymerization (DPn) of the PST block via increasing polymerization times (in a poor solvent) as determined by transmission electron microscopy (TEM) and dynamic light scattering (DLS) measurements. In parallel, a guest molecule (Nile Red) is encapsulated during the polymerization without disturbing the morphology or the polymerization kinetics.</description>
  </descriptions>
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