1 Ocak 2014 Dergi makalesi Açık Erişim

Sahiner, Nurettin; Sel, Kivanc; Ozturk, Omer Faruk; Demirci, Sahin; Terzi, Gozde

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/64771</identifier>
  <creators>
    <creator>
      <creatorName>Sahiner, Nurettin</creatorName>
      <givenName>Nurettin</givenName>
      <familyName>Sahiner</familyName>
    </creator>
    <creator>
      <creatorName>Sel, Kivanc</creatorName>
      <givenName>Kivanc</givenName>
      <familyName>Sel</familyName>
    </creator>
    <creator>
      <creatorName>Ozturk, Omer Faruk</creatorName>
      <givenName>Omer Faruk</givenName>
      <familyName>Ozturk</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Fac Sci &amp; Arts, Dept Chem, TR-17100 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Demirci, Sahin</creatorName>
      <givenName>Sahin</givenName>
      <familyName>Demirci</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Fac Sci &amp; Arts, Dept Chem, TR-17100 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Terzi, Gozde</creatorName>
      <givenName>Gozde</givenName>
      <familyName>Terzi</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Fac Sci &amp; Arts, Dept Chem, TR-17100 Canakkale, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Facile Synthesis And Characterization Of Trimesic Acid-Cu Based Metal Organic Frameworks</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2014</publicationYear>
  <dates>
    <date dateType="Issued">2014-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/64771</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.apsusc.2014.07.023</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Metal-organic frameworks based on trimesic acid (TMA) as organic linker and Cu (II) as metal ions from different metal salts such as CuCl2, Cu(NO3)(2), CuSO4 and Cu(CH3COOH)(2) were prepared in relatively environmentally friendly media e.g., at room temperature in DI water and at the boiling point of ethanol. The prepared TMA-Cu MOFs showed very interesting porosity and optical coloring based on the source of the used metal salts and preparation medium. The prepared MOFs were characterized in terms of their porosity with BET measurements and it was found that about 850 m(2)/g for the MOF prepared from Cu(NO3)(2) salt in ethanol. The amounts of metal ions connected to TMA were determined by atomic absorption spectroscopy measurements (AAS) after dissolution of TMA-Cu MOFs by concentrated HCl treatments. From MS measurements the mole ratio of Cu(II) to TMA was found to vary between 1.5 and 2, depending on the source of metal ions and the solvent used during preparation. The structural analysis and thermal characterization of the prepared MOFs were done by using FT-IR and TGA analysis, respectively. Additionally, TMA-Cu based MOF disks were prepared and their conductivities were determined by I V measurements. The conductivity of TMA-Cu MOFs was calculated to be between 8.26E-08 and 5.29E-11 S/cm. (C) 2014 Elsevier B.V. All rights reserved.</description>
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