1 Ocak 2020 Dergi makalesi Açık Erişim

Havare, Nizam

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/6451</identifier>
  <creators>
    <creator>
      <creatorName>Havare, Nizam</creatorName>
      <givenName>Nizam</givenName>
      <familyName>Havare</familyName>
      <affiliation>Stanford Univ, Sch Humanities &amp; Sci, Dept Chem, Stanford, CA 94305 USA</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Effective Synthesis Of Bicyclodienes Via Palladium-Catalyzed Asymmetric Allylic Alkylation And Ruthenium-Catalyzed Cycloisomerization</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/6451</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.3906/kim-2004-81</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">[n.3.0]Bicycles (n = 3-6) can be synthesized using palladium-catalyzed asymmetric allylic alkylation followed by ruthenium-catalyzed cycloisomerization. New types oftriarylphosphino-1,2- diaminooxazoline ligands show the same high levels of enantioselectivity observed with Trost ligand when employed in Pd-catalyzed allylic alkylation reactions. The enyne products of these allylic alkylation reactions were further elaborated using a Ru-catalyzed redox isomerization process, for which a mechanism is proposed.</description>
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