1 Ocak 2020 Dergi makalesi Açık Erişim

Yilmaz, Veysel T.; Icsel, Ceyda; Turgut, Omer R.; Aygun, Muhittin; Evren, Enes; Ozdemir, Ismail

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    "creators": [
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        "affiliation": "Uludag Univ, Fac Arts & Sci, Dept Chem, TR-16059 Bursa, Turkey", 
        "name": "Yilmaz, Veysel T."
      }, 
      {
        "affiliation": "Uludag Univ, Fac Arts & Sci, Dept Chem, TR-16059 Bursa, Turkey", 
        "name": "Icsel, Ceyda"
      }, 
      {
        "affiliation": "Uludag Univ, Fac Arts & Sci, Dept Chem, TR-16059 Bursa, Turkey", 
        "name": "Turgut, Omer R."
      }, 
      {
        "affiliation": "Dokuz Eylul Univ, Dept Phys, Fac Sci, TR-35210 Izmir, Turkey", 
        "name": "Aygun, Muhittin"
      }, 
      {
        "affiliation": "Inonu Univ, Catalysis Res & Applicat Ctr, TR-44280 Malatya, Turkey", 
        "name": "Evren, Enes"
      }, 
      {
        "affiliation": "Inonu Univ, Catalysis Res & Applicat Ctr, TR-44280 Malatya, Turkey", 
        "name": "Ozdemir, Ismail"
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    "description": "A number of new Pd(II) saccharinate (sac) complexes bearing a range of phenyl (Ph), cyclohexyl (Cy) and alkyl (Me and Et) substituted tertiary phosphine ligands with systematically changing electronic and steric properties, namely trans-[PdCl(sac)(L)(2)] (L = PPh3 (1); PPh2Cy (3)), trans-[Pd(sac)(2)(H2O)(L)] (L = PPh3 (2); PPh2Cy (5)), trans-[Pd(sac)(2)(L)(2)] (L = PPh2Cy (4); PPhCy2 (6); PCy3 (8)), [PdCl(sac)(PCy3)(DMSO)] (7), trans-[Pd (sac)(2)(PPh2Me)(DMSO)] (9) and cis-[M(sac)(2)(L)(2)] (L= PPhMe2 (10); PPh2Et (11); PPhEt2 (12)), were synthesized and structurally characterized. The Pd(II) complexes were applied for direct C2/C5 arylation of fivemembered heteroarenes such as furan, thiophene and thiazole derivatives with aryl bromides. Notably, arylation products up to 99% yields were obtained in the presence of the Pd(II) complexes. The catalytic mechanism of the direct arylation was proposed to proceed via a Pd(0)/Pd(II) pathway, due to elimination of the sac ligand in the Pd(II) complexes during catalysis.", 
    "doi": "10.1016/j.ica.2019.119220", 
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    "journal": {
      "title": "INORGANICA CHIMICA ACTA", 
      "volume": "500"
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    "publication_date": "2020-01-01", 
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      "title": "Dergi makalesi", 
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    "title": "Synthesis, structures and catalytic activity of Pd(II) saccharinate complexes with monophosphines in direct arylation of five-membered heteroarenes with aryl bromides"
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