1 Ocak 2016 Dergi makalesi Açık Erişim

Gunsel, Armagan; Kocabas, Sibel; Bilgicli, Ahmet T.; Guney, Sevgi; Kandaz, Mehmet

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{
  "@context": "https://schema.org/", 
  "@id": 61119, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Sakarya Univ, Dept Chem, TR-54140 Esentepe, Sakarya, Turkey", 
      "name": "Gunsel, Armagan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Sakarya Univ, Dept Chem, TR-54140 Esentepe, Sakarya, Turkey", 
      "name": "Kocabas, Sibel"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Sakarya Univ, Dept Chem, TR-54140 Esentepe, Sakarya, Turkey", 
      "name": "Bilgicli, Ahmet T."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Guney, Sevgi"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Sakarya Univ, Dept Chem, TR-54140 Esentepe, Sakarya, Turkey", 
      "name": "Kandaz, Mehmet"
    }
  ], 
  "datePublished": "2016-01-01", 
  "description": "We have presented in this paper, the synthesis, characterization, photophysical properties and electrochemical characterization of water soluble phthalocyanines (Pcs) bearing 8-hydroxyquinoline-5-sulfonicacid conjugates and their cationic quaternized counterpart that play important roles their application in photodynamic therapy (PDT). The periphery and non-periphery substituted phthalocyanines show high solubility and low aggregation tendency due to bulky 8-hydroxyquinoline-5-sulfonicacid steric hindrance moieties and axially bound counter chlorine anion. Singlet oxygen quantum yields, photodegradation quantum yields, photophysical properties and also the nature of the substituent and solvent effect on the photophysical and photochemical parameters of alpha-ZnPc and beta-ZnPc are reported. In electrovalent cobalt (II) and manganese (III) compounds, metal based electron transfer reactions have been observed in addition to the common phthalocyanine ring-based electron transfer processes. The effect of point of substitution on the electrochemical properties of newly synthesized phthalocyanines substituted with 8-hydroxyquinoline-5-sulfonicacid group were evaluated. (C) 2016 Elsevier B.V. All rights reserved.", 
  "headline": "Synthesis, photophysical and electrochemical properties of water-soluble phthalocyanines bearing 8-hydroxyquinoline-5-sulfonicacid derivatives", 
  "identifier": 61119, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Synthesis, photophysical and electrochemical properties of water-soluble phthalocyanines bearing 8-hydroxyquinoline-5-sulfonicacid derivatives", 
  "url": "https://aperta.ulakbim.gov.tr/record/61119"
}