1 Ocak 2016 Dergi makalesi Açık Erişim

Ertas, Ilknur Efecan; Gulcan, Mehmet; Bulut, Ahmet; Yurderi, Mehmet; Zahmakiran, Mehmet

JSON

{
  "conceptrecid": "60946", 
  "created": "2021-03-16T01:06:40.459040+00:00", 
  "doi": "10.1016/j.micromeso.2015.12.048", 
  "files": [
    {
      "bucket": "fb9643db-9b59-46fa-b06b-0d59e3b048f1", 
      "checksum": "md5:0776dc14be5db50a9a55b056527c52c6", 
      "key": "bib-911d10f5-55d0-40a5-a085-d6b18a063046.txt", 
      "links": {
        "self": "https://aperta.ulakbim.gov.tr/api/files/fb9643db-9b59-46fa-b06b-0d59e3b048f1/bib-911d10f5-55d0-40a5-a085-d6b18a063046.txt"
      }, 
      "size": 262, 
      "type": "txt"
    }
  ], 
  "id": 60947, 
  "links": {
    "badge": "https://aperta.ulakbim.gov.tr/badge/doi/10.1016/j.micromeso.2015.12.048.svg", 
    "bucket": "https://aperta.ulakbim.gov.tr/api/files/fb9643db-9b59-46fa-b06b-0d59e3b048f1", 
    "doi": "https://doi.org/10.1016/j.micromeso.2015.12.048", 
    "html": "https://aperta.ulakbim.gov.tr/record/60947", 
    "latest": "https://aperta.ulakbim.gov.tr/api/records/60947", 
    "latest_html": "https://aperta.ulakbim.gov.tr/record/60947"
  }, 
  "metadata": {
    "access_right": "open", 
    "access_right_category": "success", 
    "communities": [
      {
        "id": "tubitak-destekli-proje-yayinlari"
      }
    ], 
    "creators": [
      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Ertas, Ilknur Efecan"
      }, 
      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Gulcan, Mehmet"
      }, 
      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Bulut, Ahmet"
      }, 
      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Yurderi, Mehmet"
      }, 
      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Zahmakiran, Mehmet"
      }
    ], 
    "description": "Ruthenium(0) nanoparticles stabilized by MIL-101 metal-organic framework (Ru/MIL-101) were prepared via gas phase infiltration of Ru(cod) (cot) (cod = 1,5-cyclooctadiene, cot = 1,3,5-cyclooctatriene) followed by hydrogenolysis of Ru(cod) (cot)@MIL-101 at 3 bar H-2 and 323 K. The resulting material was characterized by using various analytical tools including ICP-OES, EA, P-XRD, XPS, DR-UV-VIS, SEM, BFTEM, HRTEM, STEM-EDX, CO-chemisorption and N-2-adsorption-desorption technique, which revealed that the formation of ruthenium(0) nanoparticles (4.2 +/- 1.2 nm) mainly exist on the surface of MIL-101 by keeping the host framework intact. The application of Ru/MIL-101 in catalysis by considering their activity, selectivity and reusability was demonstrated in the phenol hydrogenation under mild conditions. Ru/MIL-101 acted as active (lower-limit TOF = 29 mol cyclohexanone/mol Ru x h; corrected TOF = 88 mol cydohexanone/mol Ru x h. at >= 90% conversion) and selective (>= 90%) catalyst in the hydrogenation of phenol to cyclohexanone in water at 323 K and 5 bar initial H-2 pressure. More importantly, the resulting ruthenium(0) nanoparticles in Ru/MIL-101 were found to be highly durable throughout the catalytic reuse in the phenol hydrogenation (retain >= 85% of their inherent activity and selectivity at 5th reuse), which makes Ru/MIL-101 a reusable catalytic material for the liquid phase mediated catalytic transformations. (C) 2015 Elsevier Inc. All rights reserved.", 
    "doi": "10.1016/j.micromeso.2015.12.048", 
    "has_grant": false, 
    "journal": {
      "pages": "94-103", 
      "title": "MICROPOROUS AND MESOPOROUS MATERIALS", 
      "volume": "226"
    }, 
    "license": {
      "id": "cc-by"
    }, 
    "publication_date": "2016-01-01", 
    "relations": {
      "version": [
        {
          "count": 1, 
          "index": 0, 
          "is_last": true, 
          "last_child": {
            "pid_type": "recid", 
            "pid_value": "60947"
          }, 
          "parent": {
            "pid_type": "recid", 
            "pid_value": "60946"
          }
        }
      ]
    }, 
    "resource_type": {
      "subtype": "article", 
      "title": "Dergi makalesi", 
      "type": "publication"
    }, 
    "title": "Metal-organic framework (MIL-101) stabilized ruthenium nanoparticles: Highly efficient catalytic material in the phenol hydrogenation"
  }, 
  "owners": [
    1
  ], 
  "revision": 1, 
  "stats": {
    "downloads": 9.0, 
    "unique_downloads": 9.0, 
    "unique_views": 57.0, 
    "version_downloads": 9.0, 
    "version_unique_downloads": 9.0, 
    "version_unique_views": 57.0, 
    "version_views": 58.0, 
    "version_volume": 2358.0, 
    "views": 58.0, 
    "volume": 2358.0
  }, 
  "updated": "2021-03-16T01:06:40.511990+00:00"
}