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Effect of boric acid doped PEDOT:PSS layer on the performance of P3HT: PCBM based organic solar cells

Yagci, Ozlem; Yesilkaya, Serco Serkis; Yuksel, Sureyya Aydin; Ongul, Fatih; Varal, Nurhan Mehmet; Kus, Mahmut; Gunes, Serap; Icelli, Orhan


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        "affiliation": "Yildiz Tekn Univ, Dept Phys, Istanbul, Turkey", 
        "name": "Yagci, Ozlem"
      }, 
      {
        "affiliation": "Yildiz Tekn Univ, Dept Phys, Istanbul, Turkey", 
        "name": "Yesilkaya, Serco Serkis"
      }, 
      {
        "affiliation": "Yildiz Tekn Univ, Dept Phys, Istanbul, Turkey", 
        "name": "Yuksel, Sureyya Aydin"
      }, 
      {
        "affiliation": "Yildiz Tekn Univ, Dept Phys, Istanbul, Turkey", 
        "name": "Ongul, Fatih"
      }, 
      {
        "affiliation": "Adv Technol Res & Applicat Ctr, Konya, Turkey", 
        "name": "Varal, Nurhan Mehmet"
      }, 
      {
        "affiliation": "Adv Technol Res & Applicat Ctr, Konya, Turkey", 
        "name": "Kus, Mahmut"
      }, 
      {
        "affiliation": "Yildiz Tekn Univ, Dept Phys, Istanbul, Turkey", 
        "name": "Gunes, Serap"
      }, 
      {
        "affiliation": "Yildiz Tekn Univ, Dept Phys, Istanbul, Turkey", 
        "name": "Icelli, Orhan"
      }
    ], 
    "description": "In this study, we fabricated PEDOT:PSS film with different concentrations 0-5 mg/ml of boric acid (H3BO3) doped PEDOT:PSS film as hole collector layer. Undoped and boric acid doped PEDOT:PSS films are prepared with spin coating technique and characterized by XRD, UV, AFM, FTIR and electrical conductivity measurements. We fabricated polymer solar cells in the form of ITO/PEDOT:PSS:H3BO3/P3HT:PCBM/Al. Results show that the open-circuit voltage (V-oc) and the fill factor (FF) increased by introducing H3BO3 as dopant into the PEDOT:PSS layer due to an increase in the work function of PEDOT: PSS layer and improvement of surface roughness, respectively. The solar cells without H3BO3 showed a power conversion efficiency PCE of 1.79% whereas the cells with H3BO3 concentration of 1.25 mg/ml in PEDOT:PSS, showed a higher performance resulting in a PCE of 2.14% under AM 1.5G illumination. (C) 2015 Elsevier B.V. All rights reserved.", 
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      "pages": "12-18", 
      "title": "SYNTHETIC METALS", 
      "volume": "212"
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