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Photocurable pentaerythritol triacrylate/lithium phenyl-2,4,6-trimethylbenzoylphosphinate-based ink for extrusion-based 3D printing of magneto-responsive materials

Erkoc, Pelin; Odeh, Yazan Nitham; Alrifai, Nada; Zirhli, Onur; Akdogan, Nilay Gunduz; Yildiz, Burcin; Misirlioglu, Ibrahim Burc; Akdogan, Ozan


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  <dc:creator>Erkoc, Pelin</dc:creator>
  <dc:creator>Odeh, Yazan Nitham</dc:creator>
  <dc:creator>Alrifai, Nada</dc:creator>
  <dc:creator>Zirhli, Onur</dc:creator>
  <dc:creator>Akdogan, Nilay Gunduz</dc:creator>
  <dc:creator>Yildiz, Burcin</dc:creator>
  <dc:creator>Misirlioglu, Ibrahim Burc</dc:creator>
  <dc:creator>Akdogan, Ozan</dc:creator>
  <dc:date>2020-01-01</dc:date>
  <dc:description>Recent advances in additive manufacturing made it feasible to fabricate products with desired shapes and features. Herein, a new, photocurable 3D printer ink mainly based on pentaerythritol triacrylate (PETA) is reported. To achieve rapid curing needed for 3D printing process, high performance water-soluble photoinitiator, lithium phenyl-2,4,6-trimethylbenzoylphosphinate (LAP), was emulsified in PETA monomers and this suspension was evaluated for its polymerization kinetics by exposing to 395 nm UV-light. The distinct influences of LAP and triethanolamine (TEA) concentrations on photo-polymerization and printability were examined and an optimum concentration for extrusion-based 3D printing was found to be 10 mM and 1.62 M for LAP and TEA, respectively. Synthesized PETA-based 3D printer ink was functionalized by dispersing magnetic particles/flakes into the mixture, and consequently, a magneto responsive ink was obtained to be used in specialized applications. A ring-shaped structure embedded with micron sized iron flakes was printed as a prototype. This study presents a versatile photo-curable polymer formulation with possible translation to high performance 3D printing of customizable shapes that can be utilized in a wide range of areas such as micro-robotics and medical science.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/5925</dc:identifier>
  <dc:identifier>oai:zenodo.org:5925</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF APPLIED POLYMER SCIENCE 137(35)</dc:source>
  <dc:title>Photocurable pentaerythritol triacrylate/lithium phenyl-2,4,6-trimethylbenzoylphosphinate-based ink for extrusion-based 3D printing of magneto-responsive materials</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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