1 Ocak 2016 Dergi makalesi Açık Erişim

Kanberoglu, Esra; Tanyeli, Cihangir

Dublin Core

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  <dc:creator>Kanberoglu, Esra</dc:creator>
  <dc:creator>Tanyeli, Cihangir</dc:creator>
  <dc:date>2016-01-01</dc:date>
  <dc:description>A family of chiral bifunctional acid-/base-type quinine/squaramide organocatalysts is shown to be highly active promoters of the conjugate addition of 1-nitropropane to various trans--nitroalkenes. The cooperation of the quinine and the sterically encumbered squaramide moieties catalyzed the Michael addition reactions at 0 degrees C by using a catalyst loading of only 2mol% to afford the 1,3-dinitro Michael adducts with excellent enantioselectivity and diastereoselectivity (up to 95%ee and syn/anti isomers up to 96:4).</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/56251</dc:identifier>
  <dc:identifier>oai:zenodo.org:56251</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>ASIAN JOURNAL OF ORGANIC CHEMISTRY 5(1) 114-119</dc:source>
  <dc:title>Enantioselective Michael Addition of Nitroalkanes to Nitroalkenes Catalyzed by Chiral Bifunctional Quinine-Based Squaramides</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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