Dergi makalesi Açık Erişim

Readily accessible mesoporous silica nanoparticles supported chiral urea-amine bifunctional catalysts for enantioselective reactions

Gok, Yasar; Aykut, Irem Tutkum; Gok, Halil Zeki


MARC21 XML

<?xml version='1.0' encoding='UTF-8'?>
<record xmlns="http://www.loc.gov/MARC21/slim">
  <leader>00000nam##2200000uu#4500</leader>
  <datafield tag="245" ind1=" " ind2=" ">
    <subfield code="a">Readily accessible mesoporous silica nanoparticles supported chiral urea-amine bifunctional catalysts for enantioselective reactions</subfield>
  </datafield>
  <datafield tag="909" ind1="C" ind2="4">
    <subfield code="p">APPLIED ORGANOMETALLIC CHEMISTRY</subfield>
    <subfield code="v">34</subfield>
    <subfield code="n">12</subfield>
  </datafield>
  <controlfield tag="001">5553</controlfield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="a">user-tubitak-destekli-proje-yayinlari</subfield>
  </datafield>
  <datafield tag="520" ind1=" " ind2=" ">
    <subfield code="a">The main objective of this study is to develop readily accessible and recyclable solid catalysts for enantioselective reactions. To achieve this, magnetic MCM-41 and non-magnetic SBA-15 mesoporous supports were prepared, then mesoporous silica supported chiral urea-amine bifunctional catalysts were synthesized by grafting of chiral urea-amine ligand onto SBA-15 and magnetic MCM-41. The magnetic and non-magnetic supports and so-prepared solid catalysts were characterized by using different methods such as N(2)sorption measurements, Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscope-energy dispersive X-ray analysis (FESEM-EDX), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). Results showed that (1R, 2R) or (1S, 2S)-1,2-diphenylethane-1,2-diamine was successively immobilized onto magnetic MCM-41 and SBA-15 pores. The heterogeneous chiral solid catalysts and their homogenous counterparts exhibited high activities both enantioselective transfer hydrogenation reaction (up to 99% conversion and 65%ee) and enantioselective Michael reaction (up to 98% conversion and 26%ee). Moreover, the SBA-15 supported solid catalysts were separated from the reaction mixture by simple filtration, whereas the magnetic MCM-41 supported solid catalysts were separated by simple magnetic decantation and reused in three consecutive catalytic experiments.</subfield>
  </datafield>
  <datafield tag="650" ind1="1" ind2="7">
    <subfield code="2">opendefinition.org</subfield>
    <subfield code="a">cc-by</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="u">Burdur Mehmet Akif Ersoy Univ, Bucak Fac Technol, Dept Biomed Engn, TR-15300 Bucak, Burdur, Turkey</subfield>
    <subfield code="a">Aykut, Irem Tutkum</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="u">Burdur Mehmet Akif Ersoy Univ, Bucak Fac Technol, Dept Biomed Engn, TR-15300 Bucak, Burdur, Turkey</subfield>
    <subfield code="a">Gok, Halil Zeki</subfield>
  </datafield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="b">article</subfield>
    <subfield code="a">publication</subfield>
  </datafield>
  <datafield tag="542" ind1=" " ind2=" ">
    <subfield code="l">open</subfield>
  </datafield>
  <datafield tag="100" ind1=" " ind2=" ">
    <subfield code="u">Burdur Mehmet Akif Ersoy Univ, Bucak Fac Technol, Dept Biomed Engn, TR-15300 Bucak, Burdur, Turkey</subfield>
    <subfield code="a">Gok, Yasar</subfield>
  </datafield>
  <datafield tag="260" ind1=" " ind2=" ">
    <subfield code="c">2020-01-01</subfield>
  </datafield>
  <controlfield tag="005">20210315061335.0</controlfield>
  <datafield tag="909" ind1="C" ind2="O">
    <subfield code="o">oai:zenodo.org:5553</subfield>
    <subfield code="p">user-tubitak-destekli-proje-yayinlari</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="z">md5:22f5b7dc6b15105861350f3d8d1bdb18</subfield>
    <subfield code="s">212</subfield>
    <subfield code="u">https://aperta.ulakbim.gov.trrecord/5553/files/bib-6488269f-89a0-4280-beda-ed1620bd8631.txt</subfield>
  </datafield>
  <datafield tag="540" ind1=" " ind2=" ">
    <subfield code="u">http://www.opendefinition.org/licenses/cc-by</subfield>
    <subfield code="a">Creative Commons Attribution</subfield>
  </datafield>
  <datafield tag="024" ind1=" " ind2=" ">
    <subfield code="a">10.1002/aoc.6015</subfield>
    <subfield code="2">doi</subfield>
  </datafield>
</record>
44
7
görüntülenme
indirilme
Görüntülenme 44
İndirme 7
Veri hacmi 1.5 kB
Tekil görüntülenme 42
Tekil indirme 7

Alıntı yap