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Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)(3)(bpy)L]PF6 type novel manganese complexes

Ustun, Elvan; Koc, Sefika; Demir, Serpil; Ozdemir, Ismail


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{
  "@context": "https://schema.org/", 
  "@id": 54135, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Ordu Univ, Fac Art & Sci, Dept Chem, TR-52200 Ordu, Turkey", 
      "name": "Ustun, Elvan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ordu Univ, Fac Art & Sci, Dept Chem, TR-52200 Ordu, Turkey", 
      "name": "Koc, Sefika"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Inonu Univ, Fac Sci, Dept Chem, TR-44280 Malatya, Turkey", 
      "name": "Demir, Serpil"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Inonu Univ, Fac Sci, Dept Chem, TR-44280 Malatya, Turkey", 
      "name": "Ozdemir, Ismail"
    }
  ], 
  "datePublished": "2016-01-01", 
  "description": "Novel manganese(I) carbonyl complexes of the general formula [Mn(CO)(3)(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-methylbenzyl)imidazoline, N-(3-methylbenzyl)imidazoline, N-(4-methylbenzyl)imidazoline, N-(2,4,6-trimethylbenzyl)imidazoline) were synthesized and characterized by analytical (LC-MS spectrometry and elemental analysis) and spectroscopic (H-1 NMR, C-13 NMR, cosy2D-NMR, infrared) methods. The CO-releasing properties of these complexes were investigated with myoglobin assay. The DFT/TDDFT calculations were made by ORCA package program with both BP86 and B3LYP functionals. (C) 2016 Elsevier B.V. All rights reserved.", 
  "headline": "Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)(3)(bpy)L]PF6 type novel manganese complexes", 
  "identifier": 54135, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Carbon monoxide-releasing properties and DFT/TDDFT analysis of [Mn(CO)(3)(bpy)L]PF6 type novel manganese complexes", 
  "url": "https://aperta.ulakbim.gov.tr/record/54135"
}
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