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Bicyclic N-heterocyclic carbene (NHC) ligand precursors and their palladium complexes

Guemuesada, Rukiye; Guenay, M. Emin; Ozdemir, Namik; Cetinkaya, Bekir


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{
  "@context": "https://schema.org/", 
  "@id": 53929, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Adnan Menderes Univ, Fac Arts & Sci, Dept Chem, Aydin, Turkey", 
      "name": "Guemuesada, Rukiye"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Adnan Menderes Univ, Fac Arts & Sci, Dept Chem, Aydin, Turkey", 
      "name": "Guenay, M. Emin"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ondokuz Mayis Univ, Dept Secondary Sch Sci & Math Educ, Fac Educ, Samsun, Turkey", 
      "name": "Ozdemir, Namik"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ege Univ, Dept Chem, Fac Sci, Izmir, Turkey", 
      "name": "Cetinkaya, Bekir"
    }
  ], 
  "datePublished": "2016-01-01", 
  "description": "Eight bicyclic amidinium precursors (3), prepared from R,S-tmcp (R,S-tmcp: (1R,3S)-diamino-1,2,2-trimethylcyclopentane) were described. Only five of the precursors (3a-e) could be converted to palladium complexes, (PdX2(6,7-NHC)PEPPSI) (4) by treatment with PdCl2, K2CO3, and pyridine (additional KBr was used for (PdBr2(6,7-NHC)PEPPSI)). The salts and complexes were fully characterized by spectroscopic methods and X-ray crystallography.", 
  "headline": "Bicyclic N-heterocyclic carbene (NHC) ligand precursors and their palladium complexes", 
  "identifier": 53929, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Bicyclic N-heterocyclic carbene (NHC) ligand precursors and their palladium complexes", 
  "url": "https://aperta.ulakbim.gov.tr/record/53929"
}
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