1 Ocak 2017 Dergi makalesi Açık Erişim

Karuk Elmas, Aukriye Nihan; Ozen, Furkan; Koran, Kenan; Yilmaz, Ibrahim; Gorgulu, Ahmet Orhan; Erdemir, Serkan

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        "affiliation": "Karamanoglu Mehmetbey Univ, Kamil Ozdag Sci Fac, TR-70100 Karaman, Turkey", 
        "name": "Karuk Elmas, Aukriye Nihan"
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      {
        "affiliation": "Firat Univ, Fac Sci, TR-23119 Elazig, Turkey", 
        "name": "Ozen, Furkan"
      }, 
      {
        "affiliation": "Firat Univ, Fac Sci, TR-23119 Elazig, Turkey", 
        "name": "Koran, Kenan"
      }, 
      {
        "affiliation": "Karamanoglu Mehmetbey Univ, Kamil Ozdag Sci Fac, TR-70100 Karaman, Turkey", 
        "name": "Yilmaz, Ibrahim"
      }, 
      {
        "affiliation": "Firat Univ, Fac Sci, TR-23119 Elazig, Turkey", 
        "name": "Gorgulu, Ahmet Orhan"
      }, 
      {
        "affiliation": "Selcuk Univ, Fac Sci, TR-42075 Konya, Turkey", 
        "name": "Erdemir, Serkan"
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    ], 
    "description": "Solvent free synthesis of 6,7-dihydroxy-3-(3-chlorophenyl) coumarin (CFHC) was designed and obtained by the interaction of 2-(2,4,5-trimethoxyphenyl)-1-(3-chlorophenyl)acrylonitrile with pyridinium hydrochloride in the presence of silica gel by using microwave irradiation. The characterization of CFHC was confirmed by FT-IR, H-1, C-13, C-13-APT and 2D HETCOR spectroscopy methods. The optical behavior of CFHC towards metal ions was investigated by UV-visible and fluorescence spectroscopy. CFHC showed \"on-off\" type fluorescence response towards Cu2+ with high selectivity in aqueous solution (CH3CN/H2O, 9/1, v/v). Once binding with Cu2+, CFHC-Cu2+ complex also displayed high selectivity for sulfide, resulting in \"off-on\" type sensing of sulfide anion.", 
    "doi": "10.1007/s10895-016-1972-3", 
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    "journal": {
      "issue": "2", 
      "pages": "463-471", 
      "title": "JOURNAL OF FLUORESCENCE", 
      "volume": "27"
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      "id": "cc-by"
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    "publication_date": "2017-01-01", 
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    "title": "Coumarin Based Highly Selective \"off-on-off\" Type Novel Fluorescent Sensor for Cu2+ and S2- in Aqueous Solution"
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