1 Ocak 2017 Dergi makalesi Açık Erişim

Arici, Mursel; Yesilel, Okan Zafer; Tas, Murat

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/49503</identifier>
  <creators>
    <creator>
      <creatorName>Arici, Mursel</creatorName>
      <givenName>Mursel</givenName>
      <familyName>Arici</familyName>
      <affiliation>Eskisehir Osmangazi Univ, Fac Arts &amp; Sci, Dept Chem, TR-26480 Eskisehir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yesilel, Okan Zafer</creatorName>
      <givenName>Okan Zafer</givenName>
      <familyName>Yesilel</familyName>
      <affiliation>Eskisehir Osmangazi Univ, Fac Arts &amp; Sci, Dept Chem, TR-26480 Eskisehir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tas, Murat</creatorName>
      <givenName>Murat</givenName>
      <familyName>Tas</familyName>
      <affiliation>Ondokuz Mayis Univ, Fac Educ, Dept Sci Educ, TR-55139 Samsun, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Cd(Ii)-Coordination Polymers Based On Tetracarboxylic Acid And Diverse Bis(Imidazole) Ligands: Synthesis, Structural Diversity And Photoluminescence Properties</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2017</publicationYear>
  <dates>
    <date dateType="Issued">2017-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/49503</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.jssc.2016.10.015</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Three new Cd(II)-coordination polymers, namely, {[Cd-2(mu(6)-ao(2)btc)(mu-1,5-bipe)(2)].2H(2)O}(n) (1), {[Cd-2(mu(6)-ao(2)btc) (mu-1,4-bix)(2)](n)-2DMF} (2) and {[Cd-2(mu(8)-abtc)(mu-1,4-betix)].DMF.H2O}(n) (3) (ao(2)btc=di-oxygenated form of 3,3',5,5'-azobenzenetetracarboxylate, 1,5-bipe: 1,5-bis(imidazol-lyl)pentane, 1,4-bix=1,4-bis(imidazol-lylmethyl)benzene, 1,4-betix=1,4-bis(2-ethylimidazol-lylmethyl)benzene) were synthesized with 3,3',5,5'-azo-benzenetetracarboxylic acid and flexible, semi-flexible and semi-flexible substituted bis(imidazole) linkers. They were characterized by IR spectroscopy, elemental analysis, single-crystal X-ray diffraction, powder X-ray diffractions (PXRD) and thermal analyses (TG/DTA). Complexes 1-3 exhibited structural diversities depending on flexible, semi-flexible and semi-flexible substituted bis(imidazole) ligands. Complex 1 was 2D structure with 3,6L18 topology. Complex 2 had a 3D pillar-layered framework with the rare sqc27 topology. When semi flexible substituted bis(imidazole) linker was used, 3D framework of complex 3 was obtained with the paddlewheel Cd-2(CO2)(4)-type binuclear SBU. Moreover, thermal and photoluminescence properties of the complexes were determined in detailed.</description>
  </descriptions>
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