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Catalytic wet air oxidation of butyric acid and maleic acid solutions over noble metal catalysts prepared on TiO2

Dukkanci, M.; Gunduz, G.


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/42999</identifier>
  <creators>
    <creator>
      <creatorName>Dukkanci, M.</creatorName>
      <givenName>M.</givenName>
      <familyName>Dukkanci</familyName>
      <affiliation>Ege Univ, Dept Chem Engn, TR-35100 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gunduz, G.</creatorName>
      <givenName>G.</givenName>
      <familyName>Gunduz</familyName>
      <affiliation>Ege Univ, Dept Chem Engn, TR-35100 Izmir, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Catalytic Wet Air Oxidation Of Butyric Acid And Maleic Acid Solutions Over Noble Metal Catalysts Prepared On Tio2</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2009</publicationYear>
  <dates>
    <date dateType="Issued">2009-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/42999</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.catcom.2008.12.022</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The catalytic wet air oxidation (CWAO) of butyric and maleic acids was carried out in a batch reactor operated at 333 K and at atmospheric pressure. Noble metals (platinum, palladium and ruthenium) supported on TiO2 were used as catalysts as well as commercial Pt/Al2O3, Maleic and butyric acids could be oxidized only into intermediates on the commercial Pt/Al2O3 catalysts with a conversion of 11% and 7.9%, respectively. Total oxidation to CO2 ranged from 0.0% to 0.35% for butyric acid (BA) and from 0.4% to 1.7% for maleic acid (MA). Intermediate products were oxalic and formic acids. In BA oxidation, acetic acid was also detected. (C) 2008 Elsevier B.V. All rights reserved.</description>
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