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Influence of Dispersing Agents on the Solubility of Perovskites in Water

Sakar-Deliormanli, Aylin; Celik, Erdal; Polat, Mehmet


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/41671</identifier>
  <creators>
    <creator>
      <creatorName>Sakar-Deliormanli, Aylin</creatorName>
      <givenName>Aylin</givenName>
      <familyName>Sakar-Deliormanli</familyName>
      <affiliation>Izmir Inst Technol, Dept Chem Engn, TR-35430 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Celik, Erdal</creatorName>
      <givenName>Erdal</givenName>
      <familyName>Celik</familyName>
      <affiliation>Dokuz Eylul Univ, Dept Met &amp; Mat Engn, Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Polat, Mehmet</creatorName>
      <givenName>Mehmet</givenName>
      <familyName>Polat</familyName>
      <affiliation>Izmir Inst Technol, Dept Chem Engn, TR-35430 Izmir, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Influence Of Dispersing Agents On The Solubility Of Perovskites In Water</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2009</publicationYear>
  <dates>
    <date dateType="Issued">2009-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/41671</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1080/01932690802553957</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this study, solubility behavior of lead magnesium niobate (PMN) powders in water was investigated in the presence of pure polyacrylic acid and polyacrylic acid/polyethylene oxide comb polymers. Experiments were performed by measuring the solubility of PMN in terms of the concentration of Pb+2 and Mg+2 ions in supernatant as a function of pH and dispersing agent dosage. The concentrations of the metal ions in supernatant were found to be affected by the dispersant concentration, stirring time and the suspension pH. Results revealed that both dispersing agents enhance the cation dissolution from PMN surface at pH 9 due to weak (reversible) adsorption and complexation of Pb+2 and Mg+2 by carboxylate groups. On the other hand, under acidic conditions cation dissolution from PMN is inhibited and this was attributed to the strong adsorption of dispersing agents onto the powder surface and formation of a dense polymer layer.</description>
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