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Schiff base substitute polyphenol and its metal complexes derived from o-vanillin with 2,3-diaminopyridine: synthesis, characterization, thermal, and conductivity properties

Kaya, Ismet; Bilici, Ali; Guel, Murat


DataCite XML

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/40291</identifier>
  <creators>
    <creator>
      <creatorName>Kaya, Ismet</creatorName>
      <givenName>Ismet</givenName>
      <familyName>Kaya</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Fac Sci &amp; Arts, Dept Chem, TR-17020 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Bilici, Ali</creatorName>
      <givenName>Ali</givenName>
      <familyName>Bilici</familyName>
      <affiliation>Ankara Univ, Fac Sci, Dept Chem, TR-06100 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Guel, Murat</creatorName>
      <givenName>Murat</givenName>
      <familyName>Guel</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Fac Sci &amp; Arts, Dept Chem, TR-17020 Canakkale, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Schiff Base Substitute Polyphenol And Its Metal Complexes Derived From O-Vanillin With 2,3-Diaminopyridine: Synthesis, Characterization, Thermal, And Conductivity Properties</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2008</publicationYear>
  <dates>
    <date dateType="Issued">2008-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/40291</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/pat.1073</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Poly-2,3-bis[(2-hydroxy-3-methoxyphenyl)methylene]diamino pyridine (PHMPMDAP) that a new Schiff base polymer has been synthesized and characterized by spectroscopy, elemental, and thermal analyses techniques. This azomethine polymer was found to form complexes readily with Cu(II), Zn(II), Co(II), Pb(II), and Fe(II). From IR and UV-Vis studies, the phenolic oxygen and imine nitrogen of the ligand were found to be the coordination sites. Thermogravimetric analysis (TGA) data indicate the polymer to be more stable than the monomer. The structure of the polymer obtained was confirmed by FT-IR, UV-ViS, C-13-NMR, and H-1-NMR. Characterization was undertaken by TGA, size exclusion chromatography (SEC), and solubility tests. Also, electrical conductivities of PHMPMDAP and polymer-metal complexes are measured by four probe technique. Copyright (C) 2008 John Wiley &amp;amp; Sons, Ltd.</description>
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