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Polystyrene functionalized carbazole and electrochromic device application

Oral, Ayhan; Koyuncu, Sermet; Kaya, Ismet


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/39741</identifier>
  <creators>
    <creator>
      <creatorName>Oral, Ayhan</creatorName>
      <givenName>Ayhan</givenName>
      <familyName>Oral</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Dept Chem, Fac Sci &amp; Arts, TR-17020 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Koyuncu, Sermet</creatorName>
      <givenName>Sermet</givenName>
      <familyName>Koyuncu</familyName>
    </creator>
    <creator>
      <creatorName>Kaya, Ismet</creatorName>
      <givenName>Ismet</givenName>
      <familyName>Kaya</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Dept Chem, Fac Sci &amp; Arts, TR-17020 Canakkale, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Polystyrene Functionalized Carbazole And Electrochromic Device Application</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2009</publicationYear>
  <dates>
    <date dateType="Issued">2009-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/39741</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.synthmet.2009.04.026</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
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  <descriptions>
    <description descriptionType="Abstract">Polystyrene (PS) functionalized carbazole macromonomer was synthesized and polymerized by electrochemical oxidative polymerization on the ITO-glass surface. The structure of the macromonomer was elucidated by (1)H NMR, FT-IR, UV-Vis and cyclic voltammetry (CV). The spectro-electrochemical and electrochromic properties of the polymer film were investigated. Also the greenish blue colored film converted to dark blue color by the applying potential. Polystyrene-carbazole/polyethylenedioxythiophene (PS-Carb/PEDOT) electrochromic device was assembled in sandwich configuration: ITO-coated glass/anodically coloring polymer (PS-Carb)//gel electrolyte//cathodically coloring polymer (PEDOT)/ITO-coated glass. According to kinetic studies of this device, the optical contrast Delta T% at 640 nm between -1.0 and +2.0V with a residence time of 10s was found to be 38% and switching time was measured as 1.1s. (C) 2009 Elsevier B.V. All rights reserved.</description>
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