1 Ocak 2008 Dergi makalesi Açık Erişim

Kahveci, Muhammet U.; Tasdelen, M. Atilla; Cook, Wayne D.; Yagci, Yusuf

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/38817</identifier>
  <creators>
    <creator>
      <creatorName>Kahveci, Muhammet U.</creatorName>
      <givenName>Muhammet U.</givenName>
      <familyName>Kahveci</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, Fac Sci &amp; Letters, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tasdelen, M. Atilla</creatorName>
      <givenName>M. Atilla</givenName>
      <familyName>Tasdelen</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, Fac Sci &amp; Letters, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Cook, Wayne D.</creatorName>
      <givenName>Wayne D.</givenName>
      <familyName>Cook</familyName>
      <affiliation>Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia</affiliation>
    </creator>
    <creator>
      <creatorName>Yagci, Yusuf</creatorName>
      <givenName>Yusuf</givenName>
      <familyName>Yagci</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, Fac Sci &amp; Letters, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Photoinitiated Cationic Polymerization Of Mono And Divinyl Ethers In Aqueous Medium Using Ytterbium Triflate As Lewis Acid</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2008</publicationYear>
  <dates>
    <date dateType="Issued">2008-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/38817</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/macp.200800304</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Photoinitiated cationic polymerization of vinyl ethers in aqueous medium by using diphenyliodonium iodide (DPII) in the presence of a water-tolerant Lewis acid, ytterbium triflate (Yb(OTf)(3)), was reported. The polymerizations were performed in heterogeneous systems consisting of an aqueous phase containing Yb(OTf)(3) and photoinitiator and an organic phase of acetonitrile containing monomer. The polymerization consists of two-steps; (i) photoinduced adduct formation and hi) subsequent propagation with the aid of Yb(OTf)(3). The fast polymerization exhibited an explosive character so that the monomer conversion and molecular weights of the resulting polymers are very dependent on the experimental conditions, such as temperature, stirring manner and rate.</description>
  </descriptions>
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