1 Ocak 2018 Dergi makalesi Açık Erişim

Babur, Banu; Seferoglu, Nurgul; Seferoglu, Zeynel

JSON-LD (schema.org)

{
  "@context": "https://schema.org/", 
  "@id": 34031, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Gazi Univ, Dept Chem, TR-06500 Ankara, Turkey", 
      "name": "Babur, Banu"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gazi Univ, Inst Sci & Technol, Adv Technol Dept, Ankara, Turkey", 
      "name": "Seferoglu, Nurgul"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Gazi Univ, Dept Chem, TR-06500 Ankara, Turkey", 
      "name": "Seferoglu, Zeynel"
    }
  ], 
  "datePublished": "2018-01-01", 
  "description": "A novel coumarin based fluorescence anion chemosensor (P-1) bearing pyrazolone as a receptoric part was synthesized and characterized by using FT-IR, H-1/C-13 NMR and HRMS for the purpose of recognition of anions in DMSO. P-1 has four tautomeric structures and the most stable tautomeric form of P-1 was determined experimentally and theoretically. The chemosensor P-1 consists two receptoric parts as free amide N-H and enamine N-H which is stabilized intramolecular H-bonding with coumarin carbonyl oxygen. P-1 interacts selectively with fluoride anion via amide N-H. The selectivity and sensitivity of probe to various anions were determined with spectrophotometric and H-1 NMR titration techniques as experimentally and all results were also explained by theoretical calculations. (C) 2018 Elsevier B.V. All rights reserved.", 
  "headline": "A coumarin-pyrazolone based fluorescent probe for selective colorimetric and fluorimetric fluoride detection: Synthesis, spectroscopic properties and DFT calculations", 
  "identifier": 34031, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "A coumarin-pyrazolone based fluorescent probe for selective colorimetric and fluorimetric fluoride detection: Synthesis, spectroscopic properties and DFT calculations", 
  "url": "https://aperta.ulakbim.gov.tr/record/34031"
}