Dergi makalesi Açık Erişim
Yumru, Ahenk Burcu; Boroglu, Mehtap Safak; Boz, Ismail
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"affiliation": "Istanbul Univ, Dept Chem Engn, Fac Engn, TR-34320 Istanbul, Turkey",
"name": "Yumru, Ahenk Burcu"
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"affiliation": "Istanbul Univ, Dept Chem Engn, Fac Engn, TR-34320 Istanbul, Turkey",
"name": "Boroglu, Mehtap Safak"
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"affiliation": "Istanbul Univ, Dept Chem Engn, Fac Engn, TR-34320 Istanbul, Turkey",
"name": "Boz, Ismail"
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"description": "Zeolitic imidazolate framework ZIF-11 particles were prepared and mixed with Matrimid (R) 5218 polyimide, from 0 to 40 wt. % loadings. The ZIF-11 particles and the Matrimid (R) 5218 polyimide matrix were studied using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), X-Ray diffraction (XRD), infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM) techniques. Surface and cross-sectional scanning electron microscopy images of the mixed matrix membranes (MMMs) were taken to examine the dispersion of particles in the polymer matrix. No visible agglomeration between ZIF-11 particles and the polymer matrix was spotted, even at 40 wt. % ZIF-11 loading. Mixed matrix membranes were described by the measured permeabilities of H-2, CO2 and CH4 gases. Ideal gas selectivities were determined. Permeability of all gases increased with increasing ZIF-11 percentages. The permeabilities for all gases decreased at 40 wt. % loading, and the CO2/CH4, and H-2/CH4 selectivities were increased. (c) 2018 Society of Chemical Industry and John Wiley & Sons, Ltd.",
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"pages": "529-541",
"title": "GREENHOUSE GASES-SCIENCE AND TECHNOLOGY",
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"title": "ZIF-11/Matrimid (R) mixed matrix membranes for efficient CO2, CH4, and H-2 separations"
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