1 Ocak 2018 Dergi makalesi Açık Erişim

Jalal, Ahsan; Uzun, Alper

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    "description": "Performance of an ordinary supported nickel catalyst was tuned to reach an almost complete selectivity for partial hydrogenation of 1,3-butadiene by coating it with a phosphonium-type ionic liquid (IL), tributyl(methyl) phosphonium methyl sulfate, [P-4441] [MeSO4]. Thanks to high chemical and thermal stability of (P-4441) [MeSO4], the reaction conditions could be pre-optimized for high partial hydrogenation performance before the deposition of the IL coating. When the catalyst was coated with IL, it provided a total butene selectivity of 99.5 +/- 0.2%, a record high partial hydrogenation selectivity ever reported for a nickel-based catalyst. X-ray photoelectron spectroscopy results illustrated that the IL donates electrons to nickel sites and makes them selective for partial hydrogenation. The conductor like screening model for realistic solvents (COSMO-RS) calculations indicated that the IL coating also exerts a filter effect, which helps to maintain this high partial hydrogenation selectivity at all conversion levels.", 
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    "journal": {
      "pages": "321-326", 
      "title": "APPLIED CATALYSIS A-GENERAL", 
      "volume": "562"
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    "publication_date": "2018-01-01", 
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    "title": "An ordinary nickel catalyst becomes completely selective for partial hydrogenation of 1,3-butadiene when coated with tributyl(methyl) phosphonium methyl sulfate"
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