1 Ocak 2018 Dergi makalesi Açık Erişim

Yilmazoglu, Emre; Akgun, Mesut

Citation Style Language JSON

{
  "DOI": "10.1016/j.supflu.2017.08.015", 
  "abstract": "In this study, orange peel oil which had been produced by cold press technique was processed. The catalytic reaction of limonene composed of 90-95% of the orange peel oil carried out in different supercritical alcohols, and it was obtained the compound p-cymene mainly. The experiments processed in a packed bed reactor using Pt/Al2O3, Ni/AAl(2)O(3)and Pd/AAl(2)O(3) catalysts in over supercritical conditions of ethanol and 2-propanol. Experiments of reaction time, temperature and pressure scanning were carried out in the ranges of 10-50 s, 245-340 `'C and 6.5-12.5 MPa, respectively. It was observed that Ni/AAl(2)O(3) was ineffective to the conversion of limonene. However, when Pd/AAl(2)O(3) and Pt/AAl(2)O(3) catalysts were used, p-cymene was produced mainly. Especially, when Pd/AAl(2)O(3) catalyst was used, it was detected that limonene converted completely and obtained p-cymene in yield of 80%. Furthermore, p-cymene selectivity of Pd/AAl(2)O(3) was much better compared with Pt/ AAl(2)O(3).", 
  "author": [
    {
      "family": "Yilmazoglu", 
      "given": " Emre"
    }, 
    {
      "family": "Akgun", 
      "given": " Mesut"
    }
  ], 
  "container_title": "JOURNAL OF SUPERCRITICAL FLUIDS", 
  "id": "32501", 
  "issued": {
    "date-parts": [
      [
        2018, 
        1, 
        1
      ]
    ]
  }, 
  "page": "37-46", 
  "title": "p-Cym.ene production from orange peel oil using some metal catalyst in supercritical alcohols", 
  "type": "article-journal", 
  "volume": "131"
}