1 Ocak 2018 Dergi makalesi Açık Erişim

Kiskan, Fusun Seyma; Ozguz, Emre; Anac, Olcay; Tarakci, Nurdan; Merey, Gokce

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/31897</identifier>
  <creators>
    <creator>
      <creatorName>Kiskan, Fusun Seyma</creatorName>
      <givenName>Fusun Seyma</givenName>
      <familyName>Kiskan</familyName>
      <affiliation>Istanbul Tech Univ, Fac Sci &amp; Letters, Dept Chem, Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ozguz, Emre</creatorName>
      <givenName>Emre</givenName>
      <familyName>Ozguz</familyName>
      <affiliation>Istanbul Tech Univ, Fac Sci &amp; Letters, Dept Chem, Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Anac, Olcay</creatorName>
      <givenName>Olcay</givenName>
      <familyName>Anac</familyName>
      <affiliation>Istanbul Tech Univ, Fac Sci &amp; Letters, Dept Chem, Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tarakci, Nurdan</creatorName>
      <givenName>Nurdan</givenName>
      <familyName>Tarakci</familyName>
      <affiliation>Istanbul Tech Univ, Fac Sci &amp; Letters, Dept Chem, Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Merey, Gokce</creatorName>
      <givenName>Gokce</givenName>
      <familyName>Merey</familyName>
      <affiliation>Hitit Univ, Fac Engn, Dept Chem Engn, Corum, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthetic Strategies Towards The Carbenoid Reactions Of Alpha,Beta-Acetylenic Carbonyls</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2018</publicationYear>
  <dates>
    <date dateType="Issued">2018-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/31897</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.3906/kim-1805-65</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Catalytic reactions of alpha, beta-conjugated carbonyl compounds have been a practical tool towards the synthesis of different useful heterocyclic compounds. Despite the numerous reactions with carbon-carbon double bond conjugated carbonyls, reactions of acetylenic carbonyls are limited. In this study, efficient dioxole synthesis was carried out via acetylenic aldehydes and butadiene formation was preferred over cyclopropene formation via acetylenic esters as different functional groups on these substrates change the product distribution. Both reaction conditions (such as solvent and temperature) and electrophilic structure of metal carbenoids alter the product distribution; acceptor (A), donor-acceptor (DA), and acceptor-acceptor (AA) functionalized diazo compounds yield different product types over different mechanisms.</description>
  </descriptions>
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