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Apparent molar volumes, V-phi, of calcium acetate (Ca(CH3COO)(2)(aq)) at 273.15 to 353.15 K and pressures up to 100 MPa

Ziraman, Duygu Uysal; Safarov, Javid T.; Dogan, Ozkan Murat; Hassel, Egon P.; Uysal, Bekir Zuhtu


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/31665</identifier>
  <creators>
    <creator>
      <creatorName>Ziraman, Duygu Uysal</creatorName>
      <givenName>Duygu Uysal</givenName>
      <familyName>Ziraman</familyName>
      <affiliation>Gazi Univ, Dept Chem Engn, Fac Engn, Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Safarov, Javid T.</creatorName>
      <givenName>Javid T.</givenName>
      <familyName>Safarov</familyName>
    </creator>
    <creator>
      <creatorName>Dogan, Ozkan Murat</creatorName>
      <givenName>Ozkan Murat</givenName>
      <familyName>Dogan</familyName>
      <affiliation>Gazi Univ, Dept Chem Engn, Fac Engn, Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Hassel, Egon P.</creatorName>
      <givenName>Egon P.</givenName>
      <familyName>Hassel</familyName>
      <affiliation>Univ Rostock, Lehrstuhl Tech Thermodynam, Albert Einstein Str 2, D-18059 Rostock, Germany</affiliation>
    </creator>
    <creator>
      <creatorName>Uysal, Bekir Zuhtu</creatorName>
      <givenName>Bekir Zuhtu</givenName>
      <familyName>Uysal</familyName>
      <affiliation>Gazi Univ, Dept Chem Engn, Fac Engn, Ankara, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Apparent Molar Volumes, V-Phi, Of Calcium Acetate (Ca(Ch3Coo)(2)(Aq)) At 273.15 To 353.15 K And Pressures Up To 100 Mpa</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2018</publicationYear>
  <dates>
    <date dateType="Issued">2018-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/31665</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.2298/JSC080517049U</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Pressure, density and temperature (p, rho, T) data and apparent molar volumes, V-phi degrees, of aqueous calcium acetate solutions Ca(CH3COO)(2) (aq) over a wide range of temperatures from 273.15 to 353.15 K, pressures up to p = 100 MPa and molalities m, of 0.04918, 0.09367, 0.23797, 0.36365, 0.85923, 1.06930, 1.35223 and 1.81668 mol.kg(-1) of Ca(CH3COO)(2 )are reported. The combined expanded uncertainty of the density (rho) measurements at the 95 % confidence level with a coverage factor of k = 2 was estimated to be U-c(rho) = +/- 0.3 kg.m(-3). The measurements were realized with an Anton Paar DMA HPM vibration tube density meter. The system was calibrated using double-distilled water, aqueous NaCl solutions, methanol, toluene and acetone. An equation of state for fitting of the (p, rho, T) data of aqueous calcium acetate was developed as a function of pressure, temperature and molality. After a thorough analysis of literature values and validity of the constructed equation of state, various thermophysical properties, such as isothermal compressibility, isobaric thermal expansibility, differences in isobaric and isochoric heat capacities, thermal pressure coefficient and internal pressure at the investigated state parameter intervals were calculated.</description>
  </descriptions>
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