1 Ocak 2018 Dergi makalesi Açık Erişim

Cakici, Murat; Kilic, Hamdullah; Ulukanli, Sabri; Ekinci, Duygu

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    <subfield code="a">Evidence for involvement of cationic intermediate in epoxidation of chiral allylic alcohols and unfunctionalised alkenes catalysed by Mn-III(quinazolinone) complexes</subfield>
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    <subfield code="a">A pair of Mn-III(quinazolinone) complexes was prepared and evaluated in the catalytic epoxidation of the chiral allylic alcohols and unfunctionalised alkenes with iodosylbenzene. Epoxidation of chiral allylic alcohols with 1,3-allylic strain proceeded chemo- and diastereoselectively to give threo-epoxy alcohol (up to 99% d.r). Epoxidation of unfunctionalised alkenes by the proposed catalyst system proceeded nonselectively, as evidenced by the formation of isomerization and rearrangement products in the epoxidation of (Z)-stilbene. A three-step pathway involving a cationic intermediate is proposed for the formation of isomerization and rearrangement products. The fact that only products resulting from the cationic intermediate were detected in the oxidation of a mechanistic probe, (2-methoxy-3-vinylcyclopropyl)benzene, with Mn-III(quinazolinone) and PhIO substantiated the cationic oxygen transfer mechanism. (C) 2017 Elsevier Ltd. All rights reserved.</subfield>
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