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Investigation of structural and electrochemical properties of SrFe<sub>x</sub>Co<sub>1-x</sub>O<sub>3-δ</sub> perovskite oxides as a supercapacitor electrode material

Ahangari, Mohammad; Mostafaei, Jafar; Sayyah, Ali; Mahmoudi, Elham; Asghari, Elnaz; Coruh, Ali; Delibas, Nagihan; Niaei, Aligholi


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{
  "DOI": "10.1016/j.est.2023.107034", 
  "abstract": "<p>In this study, perovskite materials SrFexCo1-xO3-delta (SCF-x, x = 0.2, 0.5, 0.8) were synthesized by sol-gel combustion and investigated as electrode materials for supercapacitors. The crystalline structure and morphology of the synthesized samples were thoroughly investigated using X-ray Diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), Raman spectroscopy, Scanning Electron Microscope (SEM), and Energy Dispersive X-ray Spectroscopy (EDS) analyses. Partial substitution in the B-site of the perovskite structure affects the oxygen vacancy concentration and changes its electrochemical properties. Among the synthesized samples, SCF-0.8 exhibited a faradaic behavior and the highest specific capacitance (433 F center dot g(-1)) at 2 A center dot g(-1) current density. This sample also has a lower inherent resistance to ion and electron diffusion. The better electrochemical performance of SCF-0.8 is due to its morphology, perovskite crystal structure, and greater oxygen vacancy concentration. Long charge-discharge cycles were utilized to test the electrochemical stability of SCF-0.8. The specific capacitance reached around 60 % of its initial value after 2500 charge-discharge cycles.</p>", 
  "author": [
    {
      "family": "Ahangari", 
      "given": " Mohammad"
    }, 
    {
      "family": "Mostafaei", 
      "given": " Jafar"
    }, 
    {
      "family": "Sayyah", 
      "given": " Ali"
    }, 
    {
      "family": "Mahmoudi", 
      "given": " Elham"
    }, 
    {
      "family": "Asghari", 
      "given": " Elnaz"
    }, 
    {
      "family": "Coruh", 
      "given": " Ali"
    }, 
    {
      "family": "Delibas", 
      "given": " Nagihan"
    }, 
    {
      "family": "Niaei", 
      "given": " Aligholi"
    }
  ], 
  "container_title": "JOURNAL OF ENERGY STORAGE", 
  "id": "273194", 
  "issued": {
    "date-parts": [
      [
        2023, 
        1, 
        1
      ]
    ]
  }, 
  "page": "10", 
  "title": "Investigation of structural and electrochemical properties of SrFe<sub>x</sub>Co<sub>1-x</sub>O<sub>3-\u03b4</sub> perovskite oxides as a supercapacitor electrode material", 
  "type": "article-journal", 
  "volume": "63"
}
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