1 Ocak 2023 Dergi makalesi Açık Erişim

Kale, Amol M.; Biradar, Madan R.; Cho, Won-Je; Kaya, Cengiz; Bhosale, Sheshanath V.; Bhosale, Sidhanath V.; Kim, Byung Chul

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/268568</identifier>
  <creators>
    <creator>
      <creatorName>Kale, Amol M.</creatorName>
      <givenName>Amol M.</givenName>
      <familyName>Kale</familyName>
      <affiliation>Sunchon Natl Univ, Dept Adv Components &amp; Mat Engn, 255 Jungang Ro, Suncheon Si 57922, Jellanamdo, South Korea</affiliation>
    </creator>
    <creator>
      <creatorName>Biradar, Madan R.</creatorName>
      <givenName>Madan R.</givenName>
      <familyName>Biradar</familyName>
    </creator>
    <creator>
      <creatorName>Cho, Won-Je</creatorName>
      <givenName>Won-Je</givenName>
      <familyName>Cho</familyName>
      <affiliation>Korea Atom Energy Res Inst, Particle Beam Res Div, 181 Mirae Ro, Gyeongju 38180, Gyeonbuk, South Korea</affiliation>
    </creator>
    <creator>
      <creatorName>Kaya, Cengiz</creatorName>
      <givenName>Cengiz</givenName>
      <familyName>Kaya</familyName>
      <affiliation>Yildiz Tech Univ, Fac Chem &amp; Met, Dept Met &amp; Mat Engn, Istanbul, Turkiye</affiliation>
    </creator>
    <creator>
      <creatorName>Bhosale, Sheshanath V.</creatorName>
      <givenName>Sheshanath V.</givenName>
      <familyName>Bhosale</familyName>
      <affiliation>Cent Univ Karnataka, Sch Chem Sci, Dept Chem, Kalaburagi 585367, Karnataka, India</affiliation>
    </creator>
    <creator>
      <creatorName>Bhosale, Sidhanath V.</creatorName>
      <givenName>Sidhanath V.</givenName>
      <familyName>Bhosale</familyName>
    </creator>
    <creator>
      <creatorName>Kim, Byung Chul</creatorName>
      <givenName>Byung Chul</givenName>
      <familyName>Kim</familyName>
      <affiliation>Sunchon Natl Univ, Dept Adv Components &amp; Mat Engn, 255 Jungang Ro, Suncheon Si 57922, Jellanamdo, South Korea</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Unveiling A Cutting-Edge Bi-Ligand Nickel Metal-Organic Framework As An Electrode Material For Symmetric Supercapacitors</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2023</publicationYear>
  <dates>
    <date dateType="Issued">2023-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/268568</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.est.2023.109123</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">&lt;p&gt;Perylene diimide (PDI)-based MOFs feature a substantial specific capacitance, terrific cycle durability, swift charge/discharge rates, exceptional chemical as well as thermal endurance, diversity in electrode design, and inexpensive production costs. In light of these benefits, PDI-based MOFs are intriguing options for utilization in energy storage. Inspired by the distinctive features of perylene diimide-based ligands, highly conjugated and nitrogen-rich organic ligands Perylene diimide-L-dopa (PDI-L-Dopa) were incorporated to create the Ni-MOF architecture. The resulting hierarchical flower-like microspheres of bi-ligand Ni-MOF had better electron transport, conductivity, and wettability. When applied as electrode material in a three-electrode system considering a specific capacitance of 198 F/g at a current density of 1 A/g, the Ni-MOF-24 h electrode showcased beneficial electrochemical efficiency. XRD, FT-IR, and XPS were used to validate the formation of Ni-MOF and disclose the exact chemical composition and valence state inside the material. The hierarchical flower-like microsphere structure of the Ni-MOF, formed of 2D petal-like nanosheets, was revealed by FE-SEM and TEM. Additionally, when Ni-MOF-24 h electrodes used to fabricate symmetric supercapacitor (SSC), it reveals a high energy density (Ed) of 23 Wh/kg at a corresponding power density (Pd) of 600 W/kg along with extraordinary cyclic stability over 10,000 charge/discharge cycles with retaining 99 % of the initial capacitance. This research sheds light on the design and manufacture of innovative materials for long-term and efficient energy storage devices based on MOFs.&lt;/p&gt;</description>
  </descriptions>
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