1 Ocak 2022 Dergi makalesi Açık Erişim

Su, Esra; Bayazit, Gozde; Ide, Semra; Okay, Oguz

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        "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Su, Esra"
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      {
        "name": "Bayazit, Gozde"
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      {
        "name": "Ide, Semra"
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      {
        "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Okay, Oguz"
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    "description": "A self-healing and shape-memory interpenetrating polymer network (IPN) is produced by UV polymerization of n-octadecyl acrylate (C18A) monomer in a toluene solution of butyl rubber (isobutylene-isoprene rubber, IIR) using Irgacure 2959 photoinitiator at ambient temperature. IPNs containing 20-80 wt% IIR have crystalline domains formed by side-by-side packed octadecyl side chains aligned perpendicular to the poly(C18A) (PC18A) backbone. TEM images reveal that the morphology of IPNs consists of crystalline domains dispersed in a continuous amorphous matrix where the size of the dispersed phase could be adjusted between mu m and nm level by changing the amount of IIR. Calculations indicate that the effective cross-link density of IPNs is mainly determined by their crystalline domains followed by hydrophobic associations while the chemical cross-links between IIR and PC18A components are negligible. We also show that the crystalline domains acting as sacrificial bonds dissipate energy under strain leading to a significant toughness improvement. IPNs exhibit tunable melting temperature (46-50 degrees C), crystallinity (1.5-25%), Young's modulus (0.6-35 MPa), toughness (1.3-12 MPa), and a stretchability of up to 1200% by varying the amount of IIR component. What is more, they also exhibit temperature induced healing behavior with 59-77% efficiency, and an effective shape-memory function. The strategy presented here is applicable for the preparation of IPNs based on various rubbers and poly(n-alkyl (meth)acrylates) with long alkyl side chains.", 
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      "title": "EUROPEAN POLYMER JOURNAL", 
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    "publication_date": "2022-01-01", 
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    "title": "Butyl rubber-based interpenetrating polymer networks with side chain crystallinity: Self-healing and shape-memory polymers with tunable thermal and mechanical properties"
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