Dergi makalesi Açık Erişim
Kocaarslan, Azra; Kaya, Kerem; Jockusch, Steffen; Yagci, Yusuf
<?xml version='1.0' encoding='UTF-8'?> <record xmlns="http://www.loc.gov/MARC21/slim"> <leader>00000nam##2200000uu#4500</leader> <datafield tag="700" ind1=" " ind2=" "> <subfield code="a">Kaya, Kerem</subfield> <subfield code="u">Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="a">Jockusch, Steffen</subfield> <subfield code="u">Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="a">Yagci, Yusuf</subfield> </datafield> <datafield tag="909" ind1="C" ind2="4"> <subfield code="p">ANGEWANDTE CHEMIE-INTERNATIONAL EDITION</subfield> <subfield code="v">61</subfield> <subfield code="n">36</subfield> </datafield> <datafield tag="980" ind1=" " ind2=" "> <subfield code="a">user-tubitak-destekli-proje-yayinlari</subfield> </datafield> <datafield tag="540" ind1=" " ind2=" "> <subfield code="a">Creative Commons Attribution</subfield> <subfield code="u">http://www.opendefinition.org/licenses/cc-by</subfield> </datafield> <datafield tag="024" ind1=" " ind2=" "> <subfield code="a">10.1002/anie.202208845</subfield> <subfield code="2">doi</subfield> </datafield> <datafield tag="245" ind1=" " ind2=" "> <subfield code="a">Phenacyl Bromide as a Single-Component Photoinitiator: Photoinduced Step-Growth Polymerization of N-Methylpyrrole and N-Methylindole</subfield> </datafield> <datafield tag="100" ind1=" " ind2=" "> <subfield code="a">Kocaarslan, Azra</subfield> <subfield code="u">Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey</subfield> </datafield> <datafield tag="909" ind1="C" ind2="O"> <subfield code="o">oai:aperta.ulakbim.gov.tr:260987</subfield> <subfield code="p">user-tubitak-destekli-proje-yayinlari</subfield> </datafield> <datafield tag="650" ind1="1" ind2="7"> <subfield code="2">opendefinition.org</subfield> <subfield code="a">cc-by</subfield> </datafield> <datafield tag="260" ind1=" " ind2=" "> <subfield code="c">2022-01-01</subfield> </datafield> <datafield tag="856" ind1="4" ind2=" "> <subfield code="u">https://aperta.ulakbim.gov.trrecord/260987/files/bib-915f3505-0d39-4a60-b68e-0a6dc0f7e833.txt</subfield> <subfield code="z">md5:0447608f36fcc4a3ef6d0e40fefcec4d</subfield> <subfield code="s">241</subfield> </datafield> <datafield tag="542" ind1=" " ind2=" "> <subfield code="l">open</subfield> </datafield> <controlfield tag="005">20230729140428.0</controlfield> <controlfield tag="001">260987</controlfield> <datafield tag="980" ind1=" " ind2=" "> <subfield code="a">publication</subfield> <subfield code="b">article</subfield> </datafield> <datafield tag="520" ind1=" " ind2=" "> <subfield code="a">The synthesis of step-growth polymers by photoinduced methods is a challenging issue in synthetic chemistry. Here, we report a single component near UV responsive photopolymerization system for step-growth polymerization of N-methylpyrrole (MPyr) and N-methylindole (MIn) by using phenacyl bromide (PAB). The obtained high molecular weight conjugated polymers were characterized by spectral and chromatographic methods. Detailed laser flash photolysis and spectroscopic studies revealed that polymerization proceeds by successive photoinduced cleavage of PAB followed by electron transfer, proton release and coupling processes. After photolysis, chain growth continues also in daylight or dark by acidic oxidation. The structural features of the polymers were investigated. PAB single component photoinitiator enables an efficient, rapid, room temperature step-growth polymerization process of MPyr and MIn that can be applied to other conjugated monomers.</subfield> </datafield> </record>
Görüntülenme | 18 |
İndirme | 8 |
Veri hacmi | 1.9 kB |
Tekil görüntülenme | 18 |
Tekil indirme | 7 |