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Tuning the selectivity in iridium-catalyzed acceptorless dehydrogenative coupling of primary alcohols

Tabasi, Nihal S.; Genc, Sertac; Gulcemal, Derya


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        "affiliation": "Ege Univ, Chem Dept, TR-35100 Izmir, Turkey", 
        "name": "Tabasi, Nihal S."
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        "affiliation": "Ege Univ, Chem Dept, TR-35100 Izmir, Turkey", 
        "name": "Genc, Sertac"
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        "affiliation": "Ege Univ, Chem Dept, TR-35100 Izmir, Turkey", 
        "name": "Gulcemal, Derya"
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    "description": "An acceptorless dehydrogenative coupling of primary alcohols to carboxylic acids/carboxylates, esters, and Guerbet alcohols (via both homo- and cross-beta-alkylation of the alcohols) in the presence of an N-heterocyclic carbene iridium(i) catalyst was developed under aerobic conditions. The product selectivity can be easily tuned among the products with a single catalyst through simple modification of the reaction conditions, such as the catalyst and base amounts, the choice of base, and the reaction temperature.", 
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    "title": "Tuning the selectivity in iridium-catalyzed acceptorless dehydrogenative coupling of primary alcohols"
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