1 Ocak 2022 Dergi makalesi Açık Erişim

Bilgic, Mehmet B.; Kocaarslan, Azra; Kaya, Kerem; Atsay, Armagan; Svensson Grape, Erik; Chen, Jianhong; Yagci, Yusuf

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{
  "@context": "https://schema.org/", 
  "@id": 258021, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Bilgic, Mehmet B."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Kocaarslan, Azra"
    }, 
    {
      "@type": "Person", 
      "name": "Kaya, Kerem"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Atsay, Armagan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden", 
      "name": "Svensson Grape, Erik"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Stockholm Univ, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden", 
      "name": "Chen, Jianhong"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Yagci, Yusuf"
    }
  ], 
  "datePublished": "2022-01-01", 
  "description": "A straightforward method for the synthesis of a two-dimensional (2D) new copper(i) coordination polymer, namely Cu(bzpdc), containing the ligand benzophenone 4,4 '-dicarboxylate, and its effective use as catalyst for the azide-alkyne click chemistry at room temperature is reported. Zig-zag formation caused by cuprophilic interactions resulted in an unprecedented crystal structure with a very high copper content (45.5% by weight). The catalyst was stable up until 300 degrees C and tolerant to various solvents, including water. Cu(bzpdc) showed excellent catalytic activity for click reactions of several organic azides and alkynes having different functional groups at room temperature and is comparable to its homogenous analogues. The recyclability of Cu(bzpdc) was also tested and proven to be effective.", 
  "headline": "An unusual zig-zag 2D copper(i) coordination polymer as an outstanding catalyst for azide-alkyne \"click\" chemistry at room temperature", 
  "identifier": 258021, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "An unusual zig-zag 2D copper(i) coordination polymer as an outstanding catalyst for azide-alkyne \"click\" chemistry at room temperature", 
  "url": "https://aperta.ulakbim.gov.tr/record/258021"
}