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Determining the Morphology of Polystyrene-block-poly(2-y=vinylpyridine) Micellar Reactors for ZnO Nanoparticle Synthesis

El-Atwani, Osman C.; Aytun, Taner; Mutaf, Omer Faruk; Srot, Vesna; van Aken, Peter A.; Ow-Yang, Cleva W.


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        "affiliation": "Sabanci Univ, Mat Sci & Engn Program, TR-34956 Istanbul, Turkey", 
        "name": "El-Atwani, Osman C."
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      {
        "affiliation": "Sabanci Univ, Mat Sci & Engn Program, TR-34956 Istanbul, Turkey", 
        "name": "Aytun, Taner"
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      {
        "affiliation": "Sabanci Univ, Mat Sci & Engn Program, TR-34956 Istanbul, Turkey", 
        "name": "Mutaf, Omer Faruk"
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      {
        "affiliation": "Max Planck Inst Met Res, Stuttgart Ctr Transmiss Elect Microscopy, D-70569 Stuttgart, Germany", 
        "name": "Srot, Vesna"
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        "affiliation": "Max Planck Inst Met Res, Stuttgart Ctr Transmiss Elect Microscopy, D-70569 Stuttgart, Germany", 
        "name": "van Aken, Peter A."
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        "affiliation": "Sabanci Univ, Mat Sci & Engn Program, TR-34956 Istanbul, Turkey", 
        "name": "Ow-Yang, Cleva W."
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    "description": "We report the use of reverse PS-b-P2VP diblock copolymer micelles as true nanoscale-sized reactor vessels to synthesize ZnO nanoparticles. The reverse micelles were formed in toluene and then sequentially loaded with zinc acetate dihydrate and tetramethylammonium hydroxide reactants. Moreover, high spatial resolution Z-contrast imaging and EDX spectroscopy techniques were used to confirm the segregation of the Zn cation to the core of the loaded micelles. Determining the chemical distribution with high nanoscale spatial resolution is shown to complement the less direct characterization by AFM, DLS and FTIR, thus demonstrating broader implications for the characterization of hybrid nanocomposite systems.", 
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