1 Ocak 2022 Dergi makalesi Açık Erişim

Gungor, Seyit Ali; Tumer, Mehmet; Tumer, Ferhan; Kose, Muhammet; Gungor, Ozge; Purtas, Savas

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/238764</identifier>
  <creators>
    <creator>
      <creatorName>Gungor, Seyit Ali</creatorName>
      <givenName>Seyit Ali</givenName>
      <familyName>Gungor</familyName>
      <affiliation>Kahramanmaras Sutcu Imam Univ, Fac Sci &amp; Letters, Chem Dept, TR-46100 Kahramanmaras, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tumer, Mehmet</creatorName>
      <givenName>Mehmet</givenName>
      <familyName>Tumer</familyName>
      <affiliation>Kahramanmaras Sutcu Imam Univ, Fac Sci &amp; Letters, Chem Dept, TR-46100 Kahramanmaras, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tumer, Ferhan</creatorName>
      <givenName>Ferhan</givenName>
      <familyName>Tumer</familyName>
      <affiliation>Kahramanmaras Sutcu Imam Univ, Fac Sci &amp; Letters, Chem Dept, TR-46100 Kahramanmaras, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kose, Muhammet</creatorName>
      <givenName>Muhammet</givenName>
      <familyName>Kose</familyName>
      <affiliation>Kahramanmaras Sutcu Imam Univ, Fac Sci &amp; Letters, Chem Dept, TR-46100 Kahramanmaras, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gungor, Ozge</creatorName>
      <givenName>Ozge</givenName>
      <familyName>Gungor</familyName>
      <affiliation>Kahramanmaras Sutcu Imam Univ, Fac Sci &amp; Letters, Chem Dept, TR-46100 Kahramanmaras, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Purtas, Savas</creatorName>
      <givenName>Savas</givenName>
      <familyName>Purtas</familyName>
      <affiliation>Kahramanmaras Sutcu Imam Univ, Fac Sci &amp; Letters, Chem Dept, TR-46100 Kahramanmaras, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Water Soluble Porphyrin-Schiff Base Ligands And Their Metal Complexes: Synthesis, Photophysical, Electrochemical, And Chemosensor Properties</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2022</publicationYear>
  <dates>
    <date dateType="Issued">2022-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/238764</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/aoc.6534</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this work, 5-(4-aminophenyl)-10,15,20-tris(4-sulfonatophenyl)porphyrin trisodium salt was reacted with 4-R-2,6-diformyl phenol (R: -Me, -Et or -(t)butyl) to obtain dimeric porphyrin-Schiff base ligands as their sodium salts [Na-6(H5L1)-Na-6(H5L3). The Mn3+, Cu2+, and Zn2+ complexes of the water-soluble porphyrin-Schiff base ligands were also prepared, and their structures were characterized by the spectroscopic and analytical methods. The ligands exhibited H or J-aggregates with the change in pH. The water-soluble ligands showed reversible diffusion-controlled redox processes involving the pi-ring system of the porphyrin. The chemosensor properties of the ligands Na-6(H5L1)-Na-6(H5L3) towards cations or anions were studied by colorimetric and spectrophotometric methods. Na-6(H5L1) showed selective sensing abilities towards SO42- and Cu2+, while Na-6(H5L3) has selectivity for I-, Ag+, and Co2+ ions. The ligands were also tested as a fluorimetric probes for the detection of nitro-aromatic compounds [nitrobenzene (NB), 2,4-dinitrophenol (DNP) and 2,4,6-trinitrophenol (TNP)]. Na-6(H5L2) exhibits selective and sensitive sensing abilities for nitrobenzene with high quenching constants (K-sv = 3.80 x 10(6) M-1) and low detection limit (LOD = 0.0091 mu M).</description>
  </descriptions>
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