1 Ocak 2021 Dergi makalesi Açık Erişim

Romanini, Michela; Wang, YiXu; Gurpinar, Kubra; Ornelas, Gladys; Lloveras, Pol; Zhang, Yan; Zheng, Wenkai; Barrio, Maria; Aznar, Araceli; Gracia-Condal, Adria; Emre, Baris; Atakol, Orhan; Popescu, Catalin; Zhang, Hu; Long, Yi; Balicas, Luis; Lluis Tamarit, Josep; Planes, Antoni; Shatruk, Michael; Manosa, Lluis

JSON

{
  "conceptrecid": "235423", 
  "created": "2022-10-07T09:18:21.803774+00:00", 
  "doi": "10.1002/adma.202008076", 
  "files": [
    {
      "bucket": "ac2fbf11-9235-4589-8d0e-d946d08555e6", 
      "checksum": "md5:741c121b498f4112165721e0a586ba11", 
      "key": "bib-01e8e4d8-24ad-4da0-9dbb-f2bb6479f657.txt", 
      "links": {
        "self": "https://aperta.ulakbim.gov.tr/api/files/ac2fbf11-9235-4589-8d0e-d946d08555e6/bib-01e8e4d8-24ad-4da0-9dbb-f2bb6479f657.txt"
      }, 
      "size": 393, 
      "type": "txt"
    }
  ], 
  "id": 235424, 
  "links": {
    "badge": "https://aperta.ulakbim.gov.tr/badge/doi/10.1002/adma.202008076.svg", 
    "bucket": "https://aperta.ulakbim.gov.tr/api/files/ac2fbf11-9235-4589-8d0e-d946d08555e6", 
    "doi": "https://doi.org/10.1002/adma.202008076", 
    "html": "https://aperta.ulakbim.gov.tr/record/235424", 
    "latest": "https://aperta.ulakbim.gov.tr/api/records/235424", 
    "latest_html": "https://aperta.ulakbim.gov.tr/record/235424"
  }, 
  "metadata": {
    "access_right": "open", 
    "access_right_category": "success", 
    "communities": [
      {
        "id": "tubitak-destekli-proje-yayinlari"
      }
    ], 
    "creators": [
      {
        "affiliation": "Univ Barcelona, Fac Fis Marti & Franques 1, Dept Fis Mat Condensada, Barcelona 08028, Catalonia, Spain", 
        "name": "Romanini, Michela"
      }, 
      {
        "name": "Wang, YiXu"
      }, 
      {
        "affiliation": "Ankara Univ, Fac Sci, Dept Chem, TR-06100 Ankara, Turkey", 
        "name": "Gurpinar, Kubra"
      }, 
      {
        "name": "Ornelas, Gladys"
      }, 
      {
        "name": "Lloveras, Pol"
      }, 
      {
        "affiliation": "Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA", 
        "name": "Zhang, Yan"
      }, 
      {
        "affiliation": "Natl High Magnet Field Lab, Tallahassee, FL 32310 USA", 
        "name": "Zheng, Wenkai"
      }, 
      {
        "name": "Barrio, Maria"
      }, 
      {
        "name": "Aznar, Araceli"
      }, 
      {
        "affiliation": "Univ Barcelona, Fac Fis Marti & Franques 1, Dept Fis Mat Condensada, Barcelona 08028, Catalonia, Spain", 
        "name": "Gracia-Condal, Adria"
      }, 
      {
        "affiliation": "Ankara Univ, Fac Engn, Dept Engn Phys, TR-06100 Ankara, Turkey", 
        "name": "Emre, Baris"
      }, 
      {
        "affiliation": "Ankara Univ, Fac Sci, Dept Chem, TR-06100 Ankara, Turkey", 
        "name": "Atakol, Orhan"
      }, 
      {
        "affiliation": "CELLS ALBA Synchrotron, E-08290 Cerdanyola Del Valles, Catalonia, Spain", 
        "name": "Popescu, Catalin"
      }, 
      {
        "affiliation": "Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China", 
        "name": "Zhang, Hu"
      }, 
      {
        "affiliation": "Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China", 
        "name": "Long, Yi"
      }, 
      {
        "affiliation": "Natl High Magnet Field Lab, Tallahassee, FL 32310 USA", 
        "name": "Balicas, Luis"
      }, 
      {
        "name": "Lluis Tamarit, Josep"
      }, 
      {
        "affiliation": "Univ Barcelona, Fac Fis Marti & Franques 1, Dept Fis Mat Condensada, Barcelona 08028, Catalonia, Spain", 
        "name": "Planes, Antoni"
      }, 
      {
        "name": "Shatruk, Michael"
      }, 
      {
        "affiliation": "Univ Barcelona, Fac Fis Marti & Franques 1, Dept Fis Mat Condensada, Barcelona 08028, Catalonia, Spain", 
        "name": "Manosa, Lluis"
      }
    ], 
    "description": "A giant barocaloric effect (BCE) in a molecular material Fe-3(bntrz)(6)(tcnset)(6) (FBT) is reported, where bntrz = 4-(benzyl)-1,2,4-triazole and tcnset = 1,1,3,3-tetracyano-2-thioethylepropenide. The crystal structure of FBT contains a trinuclear transition metal complex that undergoes an abrupt spin-state switching between the state in which all three Fe-II centers are in the high-spin (S = 2) electronic configuration and the state in which all of them are in the low-spin (S = 0) configuration. Despite the strongly cooperative nature of the spin transition, it proceeds with a negligible hysteresis and a large volumetric change, suggesting that FBT should be a good candidate for producing a large BCE. Powder X-ray diffraction and calorimetry reveal that the material is highly susceptible to applied pressure, as the transition temperature spans the range from 318 at ambient pressure to 383 K at 2.6 kbar. Despite the large shift in the spin-transition temperature, its nonhysteretic character is maintained under applied pressure. Such behavior leads to a remarkably large and reversible BCE, characterized by an isothermal entropy change of 120 J kg(-1) K-1 and an adiabatic temperature change of 35 K, which are among the highest reversible values reported for any caloric material thus far.", 
    "doi": "10.1002/adma.202008076", 
    "has_grant": false, 
    "journal": {
      "issue": "10", 
      "title": "ADVANCED MATERIALS", 
      "volume": "33"
    }, 
    "license": {
      "id": "cc-by"
    }, 
    "publication_date": "2021-01-01", 
    "relations": {
      "version": [
        {
          "count": 1, 
          "index": 0, 
          "is_last": true, 
          "last_child": {
            "pid_type": "recid", 
            "pid_value": "235424"
          }, 
          "parent": {
            "pid_type": "recid", 
            "pid_value": "235423"
          }
        }
      ]
    }, 
    "resource_type": {
      "subtype": "article", 
      "title": "Dergi makalesi", 
      "type": "publication"
    }, 
    "science_branches": [
      "Di\u011fer"
    ], 
    "title": "Giant and Reversible Barocaloric Effect in Trinuclear Spin-Crossover Complex Fe-3(bntrz)(6)(tcnset)(6)"
  }, 
  "owners": [
    1
  ], 
  "revision": 1, 
  "stats": {
    "downloads": 6.0, 
    "unique_downloads": 6.0, 
    "unique_views": 26.0, 
    "version_downloads": 6.0, 
    "version_unique_downloads": 6.0, 
    "version_unique_views": 26.0, 
    "version_views": 26.0, 
    "version_volume": 2358.0, 
    "views": 26.0, 
    "volume": 2358.0
  }, 
  "updated": "2022-10-07T09:18:21.866448+00:00"
}