1 Ocak 2021 Dergi makalesi Açık Erişim

Yanalak, Gizem; Doganay, Fatmanur; Eroglu, Zafer; Kucukkececi, Huseyin; Aslan, Emre; Ozmen, Mustafa; Bas, Salih Zeki; Metin, Onder; Patir, Imren Hatay

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/232380</identifier>
  <creators>
    <creator>
      <creatorName>Yanalak, Gizem</creatorName>
      <givenName>Gizem</givenName>
      <familyName>Yanalak</familyName>
      <affiliation>Selcuk Univ, Dept Biochem, TR-42130 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Doganay, Fatmanur</creatorName>
      <givenName>Fatmanur</givenName>
      <familyName>Doganay</familyName>
      <affiliation>Selcuk Univ, Dept Biotechnol, TR-42130 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Eroglu, Zafer</creatorName>
      <givenName>Zafer</givenName>
      <familyName>Eroglu</familyName>
    </creator>
    <creator>
      <creatorName>Kucukkececi, Huseyin</creatorName>
      <givenName>Huseyin</givenName>
      <familyName>Kucukkececi</familyName>
      <affiliation>Koc Univ, Coll Sci, Dept Chem, TR-34450 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Aslan, Emre</creatorName>
      <givenName>Emre</givenName>
      <familyName>Aslan</familyName>
      <affiliation>Selcuk Univ, Dept Biochem, TR-42130 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ozmen, Mustafa</creatorName>
      <givenName>Mustafa</givenName>
      <familyName>Ozmen</familyName>
      <affiliation>Selcuk Univ, Dept Chem, TR-42030 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Bas, Salih Zeki</creatorName>
      <givenName>Salih Zeki</givenName>
      <familyName>Bas</familyName>
      <affiliation>Selcuk Univ, Dept Chem, TR-42030 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Metin, Onder</creatorName>
      <givenName>Onder</givenName>
      <familyName>Metin</familyName>
      <affiliation>Koc Univ, Coll Sci, Dept Chem, TR-34450 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Patir, Imren Hatay</creatorName>
      <givenName>Imren Hatay</givenName>
      <familyName>Patir</familyName>
      <affiliation>Selcuk Univ, Dept Biotechnol, TR-42130 Konya, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Ternary Nanocomposites Of Mesoporous Graphitic Carbon Nitride/Black Phosphorus/Gold Nanoparticles (Mpg-Cn/Bp-Au) For Photocatalytic Hydrogen Evolution And Electrochemical Sensing Of Paracetamol</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2021</publicationYear>
  <dates>
    <date dateType="Issued">2021-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/232380</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.apsusc.2021.149755</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">We report herein the fabrication of a novel ternary nanocomposite of mesoporous graphitic carbon nitride/black phosphorus-gold nanoparticles (mpg-CN/BP-Au) and its catalytic performance in the photocatalytic hydrogen evolution reaction (HER) and electrochemical detection of paracetamol. The photocatalytic hydrogen production rate of mpg-CN/BP-Au nanocomposite (1024 mu mol g-1 for 8 h) is compared with mpg-CN, mpg-CN/BP and mpgCN/Au in the presence of triethanolamine (TEOA) as a hole scavenger under the visible light. In addition to the photocatalytic HER application, as-prepared mpg-CN/BP-Au nanocomposite was deposited on modified glassy carbon electrode (mpg-CN/BP-Au/GCE) and for the first time tested for the detection of paracetamol (PA). Under the optimum conditions, linear range of paracetamol detection was found to be in the range of 0.3-120 mu M with a detection limit of 0.0425 mu M. mpg-CN/BP-Au/GCE provided higher electrocatalytic activity than pristine mpgCN and all other tested binary nanocomposites. The enhanced photo- and electrochemical activity of mpgCN/BP-Au/GCE are attributed to formation of heterojunction between BP and mpg-CN materials. Additionally, Au nanoparticles increase the rate of adsorption of mpg-CN/BP due to the excellent electrical properties and spillover effect. We believe that the presented design and catalysis of the ternary nanocomposite will pave a way in many photo- and electrochemical applications.</description>
  </descriptions>
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