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Cobalt(II), Zinc(II) and Cadmium(II) Coordination Polymers Assembled by Flexible 5,5 '-(But-2-ene-1,4-diylbis(oxy))diisophthalic Acid and 1,2-Bis((1H-imidazol-1-yl)methyl)benzene Ligands

Ciftci, Esengul; Erer, Hakan; Arici, Mursel; Yesilel, Okan Zafer


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{
  "@context": "https://schema.org/", 
  "@id": 232026, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Eskisehir Osmangazi Univ, Fac Sci & Letters, Dept Chem, TR-26040 Eskisehir, Turkey", 
      "name": "Ciftci, Esengul"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Eskisehir Osmangazi Univ, Fac Sci & Letters, Dept Chem, TR-26040 Eskisehir, Turkey", 
      "name": "Erer, Hakan"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Eskisehir Osmangazi Univ, Fac Sci & Letters, Dept Chem, TR-26040 Eskisehir, Turkey", 
      "name": "Arici, Mursel"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Eskisehir Osmangazi Univ, Fac Sci & Letters, Dept Chem, TR-26040 Eskisehir, Turkey", 
      "name": "Yesilel, Okan Zafer"
    }
  ], 
  "datePublished": "2021-01-01", 
  "description": "Four new two and three dimensional coordination polymers, namely, [Co-2(mu(4)-L)(mu-obix)(2)](n) (1), [Zn-2(mu(4)-L)(mu-obix)(2)](n) (2), {[Zn-2(mu(4)-L)(mu-obix)(2)]center dot 2CH(3)CN}(n) (3), and {[Cd-2(mu(4)-L)(H2O)(4)(mu-obix)](n)center dot 2H(2)O}(n) (4), where H4L = 5,5 '-(but-2-ene-1,4-diylbis(oxy))diisophthalic acid and obix = 1,2-bis((1H-imidazol-1-yl)methyl)benzene), were synthesized under solvothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analyses, infrared spectra (IR) and elemental analyses. Compounds 1 and 2 were isostructural and displayed 3D 3-fold interpenetrating frameworks with mog moganite topologies. Compound 3 featured a 2D 2-fold interpenetrating network with 3,4L13 topology. Compound 4 exhibited a 2D layer structure with 3,4-connected 3,4L13 topology. Furthermore, luminescence and thermal properties of the compounds were investigated in detail.", 
  "headline": "Cobalt(II), Zinc(II) and Cadmium(II) Coordination Polymers Assembled by Flexible 5,5 '-(But-2-ene-1,4-diylbis(oxy))diisophthalic Acid and 1,2-Bis((1H-imidazol-1-yl)methyl)benzene Ligands", 
  "identifier": 232026, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Cobalt(II), Zinc(II) and Cadmium(II) Coordination Polymers Assembled by Flexible 5,5 '-(But-2-ene-1,4-diylbis(oxy))diisophthalic Acid and 1,2-Bis((1H-imidazol-1-yl)methyl)benzene Ligands", 
  "url": "https://aperta.ulakbim.gov.tr/record/232026"
}
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