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Reaction of cycloheptatriene derivatives with 1,3-diketones in the presence of Mn(OAc)(3)

Sudemen, Mahir Burak; Zengin, Mustafa; Genc, Hayriye; Balci, Metin


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        "affiliation": "Middle E Tech Univ, Dept Chem, Fac Sci, TR-06531 Ankara, Turkey", 
        "name": "Sudemen, Mahir Burak"
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      {
        "affiliation": "Sakarya Univ, Fac Sci, Dept Chem, TR-54140 Sakarya, Turkey", 
        "name": "Zengin, Mustafa"
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      {
        "affiliation": "Sakarya Univ, Fac Sci, Dept Chem, TR-54140 Sakarya, Turkey", 
        "name": "Genc, Hayriye"
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      {
        "affiliation": "Middle E Tech Univ, Dept Chem, Fac Sci, TR-06531 Ankara, Turkey", 
        "name": "Balci, Metin"
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    "description": "The reactions of some 1,3-dicarbonyl compounds with cycloheptatriene derivatives in the presence of Mn(OAc)(3) were examined. Cycloheptatriene forms mainly [2+3] and [6+3] dihydrofuran addition products derived from cycloheptatriene. However, the reaction of acetylacetone with cycloheptatriene substituted with an electron withdrawing group exclusively gave products derived from the norcaradiene structure. The formation mechanism of the products as well as the role of the substituent attached to cycloheptatriene is discussed.", 
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