1 Ocak 2011 Dergi makalesi Açık Erişim

Dogruyol, Sevnur Keskin; Dogruyol, Zekeriya; Arsu, Nergis

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  "@context": "https://schema.org/", 
  "@id": 19215, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey", 
      "name": "Dogruyol, Sevnur Keskin"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Yildiz Tech Univ, Dept Phys, TR-34220 Istanbul, Turkey", 
      "name": "Dogruyol, Zekeriya"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey", 
      "name": "Arsu, Nergis"
    }
  ], 
  "datePublished": "2011-01-01", 
  "description": "Thioxanthone-based 9-(2-Morpholine-4yl-acetyl)-5-thia-napthasen-12-one (TX-MPM) was synthesized and characterized as a one-component novel visible photoinitiator. Its capability to act as an initiator for the polymerization of methyl methacrylate (MMA) was examined in photoreactor and also daylight. Photophysical properties: fluorescence and phosphorescence emission spectra and fluorescence quantum yield of TX-MPM (Phi(f) = 0.29) were determined. The phosphorescence lifetime was found 131 ms for TX-MPM and 110 ms for initiator-attached polymer (PMMA) at 77 K, indicated a pi ->pi* nature of the lowest triplet state. A model compound, morpholino acetonapthone was used as quencher for the triplet states of TX-MPM and the quenching rate constant was determined (k(q) = 1.26 x 10(9) M(-1)s(-1)). According to laser flash photolysis studies, intermolecular hydrogen abstraction process was more dominant path to the formation of the initiating radicals. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 4037-4043, 2011", 
  "headline": "A Thioxanthone-Based Visible Photoinitiator", 
  "identifier": 19215, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "A Thioxanthone-Based Visible Photoinitiator", 
  "url": "https://aperta.ulakbim.gov.tr/record/19215"
}