1 Ocak 2011 Dergi makalesi Açık Erişim

Besli, Serap; Coles, Simon J.; Davies, David B.; Kilic, Adem; Shaw, Robert A.

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        "affiliation": "Gebze Inst Technol, Dept Chem, Gebze, Turkey", 
        "name": "Besli, Serap"
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      {
        "affiliation": "Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England", 
        "name": "Coles, Simon J."
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      {
        "affiliation": "Univ London Birkbeck Coll, Sch Biol & Chem Sci, London WC1E 7HX, England", 
        "name": "Davies, David B."
      }, 
      {
        "affiliation": "Gebze Inst Technol, Dept Chem, Gebze, Turkey", 
        "name": "Kilic, Adem"
      }, 
      {
        "affiliation": "Univ London Birkbeck Coll, Sch Biol & Chem Sci, London WC1E 7HX, England", 
        "name": "Shaw, Robert A."
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    "description": "Cyclotriphosphazene derivatives containing a P-NHR group in the side-chain react in the presence of a strong base to form stable intermolecular bridged products. Reaction of sodium hydride with mono-spiro cyclophosphazene derivatives having a P-NH group, N3P3Cl4[O(CH2)(3)NH], (1a) or N3P3Cl4[CH3N(CH2)(3)NH], (1b) leads to formation of bis-cyclophosphazenes bridged with an eight-membered cyclophosphazene ring in an ansa arrangement (2a, 2b) whereas reaction of sodium hydride with mono-amino cyclophosphazene derivatives [N3P3Cl5(NHR), R = n-hexyl, 3a; i-Pr, 3b; Ph, 3c] give bis-cyclophosphazenes bridged with a four-membered cyclophosphazane ring in a spiro arrangement (4a-c). In the latter reaction P-O-P bridged compounds (5a-c) were also obtained as a result of hydrolysis reactions associated with the amount of moisture in the solvent tetrahydrofuran. In addition, it was found that reaction of a mixture of cyclotriphosphazene with either mono spiro compound, (1a) or (1b), in the presence of sodium hydride lead to formation of the first examples of asymmetrically-bridged cyclophosphazenes (6a-b).", 
    "doi": "10.1039/c1dt10073d", 
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      "issue": "19", 
      "pages": "5307-5315", 
      "title": "DALTON TRANSACTIONS", 
      "volume": "40"
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    "publication_date": "2011-01-01", 
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      "title": "Dergi makalesi", 
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    "title": "Bridged cyclophosphazenes resulting from deprotonation reactions of cyclotriphophazenes bearing a P-NH group"
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