1 Ocak 2011 Dergi makalesi Açık Erişim

Soyleyici, H. Can; Firinci, Erkan; Eyduran, Fatih; Akbulat, Funda; Sahin, Yuksel

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        "affiliation": "Adnan Menderes Univ, Dept Chem, TR-09010 Aydin, Turkey", 
        "name": "Soyleyici, H. Can"
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      {
        "affiliation": "Adnan Menderes Univ, Dept Chem, TR-09010 Aydin, Turkey", 
        "name": "Firinci, Erkan"
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      {
        "affiliation": "Adnan Menderes Univ, Dept Chem, TR-09010 Aydin, Turkey", 
        "name": "Eyduran, Fatih"
      }, 
      {
        "affiliation": "Adnan Menderes Univ, Dept Chem, TR-09010 Aydin, Turkey", 
        "name": "Akbulat, Funda"
      }, 
      {
        "affiliation": "Adnan Menderes Univ, Dept Chem, TR-09010 Aydin, Turkey", 
        "name": "Sahin, Yuksel"
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    "description": "Addition of LDA to a mixture of trimethylborate and dibromomethane in THF at a temperature of -78 degrees C leads to the formation of dibromomethyllithium and its capture by borate ester. CIB(OMe)(2) converts the resulting borate salt to dimethoxy(dibromomethyl)borane 2. N,N-Dimethylamino(methoxy) (dibromomethyl)borane 3 and N,N-bis(dimethylamino)(dibromomethyl)borane 4 were prepared by an amination reaction between N,N-dimethylaminotrimethylsilane and dimethoxy(dibromomethyl)borane 2. To obtain dichlorotrimethylsilylmethylborane 7 not containing the alpha-halomethyl group. N,N-bis(dimethylamino)(trimethylsilylmethyl)borane 5 was first obtained from the reaction of CIB(NMe2)(2) with an organolithium reagent. Dimethoxy(trimethylsilylmethyl)borane 6 was then prepared by methoxylation of compound 5. Finally, compound 7 was prepared by chlorination of 6 using BCl3. The chemical structures of these compounds were determined using C-13, H-1, B-11 NMR and GC/MS/MS techniques. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.", 
    "doi": "10.1016/j.saa.2010.12.066", 
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    "journal": {
      "issue": "3", 
      "pages": "1139-1142", 
      "title": "SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY", 
      "volume": "78"
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    "publication_date": "2011-01-01", 
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    "title": "A practical synthesis of novel alpha-dibromoalkyl- and trimethylsilylmethyl-aminoboranes and derivatives"
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