1 Ocak 2013 Dergi makalesi Açık Erişim

Algi, Melek Pamuk; Tirkes, Seha; Ertan, Salih; Ergun, Emine Gul Cansu; Cihaner, Atilla; Algi, Fatih

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/17485</identifier>
  <creators>
    <creator>
      <creatorName>Algi, Melek Pamuk</creatorName>
      <givenName>Melek Pamuk</givenName>
      <familyName>Algi</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, LOM, TR-17100 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tirkes, Seha</creatorName>
      <givenName>Seha</givenName>
      <familyName>Tirkes</familyName>
      <affiliation>Atilim Univ, Atilim Optoelect Mat &amp; Solar Energy Lab ATOMSEL, TR-06836 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ertan, Salih</creatorName>
      <givenName>Salih</givenName>
      <familyName>Ertan</familyName>
      <affiliation>Atilim Univ, Atilim Optoelect Mat &amp; Solar Energy Lab ATOMSEL, TR-06836 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ergun, Emine Gul Cansu</creatorName>
      <givenName>Emine Gul Cansu</givenName>
      <familyName>Ergun</familyName>
      <affiliation>Atilim Univ, Atilim Optoelect Mat &amp; Solar Energy Lab ATOMSEL, TR-06836 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Cihaner, Atilla</creatorName>
      <givenName>Atilla</givenName>
      <familyName>Cihaner</familyName>
      <affiliation>Atilim Univ, Atilim Optoelect Mat &amp; Solar Energy Lab ATOMSEL, TR-06836 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Algi, Fatih</creatorName>
      <givenName>Fatih</givenName>
      <familyName>Algi</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, LOM, TR-17100 Canakkale, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Design And Synthesis Of New 4,4 '-Difluoro-4-Bora-3A,4A-Diaza-S-Indacene Based Electrochromic Polymers</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/17485</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.electacta.2013.07.179</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Design, synthesis, optical and electrochemical properties of two novel 4,4'-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) based donor-acceptor compounds, 1 and 2, are reported in order to elucidate the structure-property relationships in BODIPY based materials. Importantly, these compounds provide opportunity to be used as crosslinkers, since they have three electroactive donor sides. Furthermore, these compounds are polymerized successfully via electrochemical polymerization. The corresponding polymers (P1 and P2) are also characterized by using electrochemical and optical methods in monomer-free electrolyte solutions. It is found that both polymers P1 and P2 exhibit reversible oxidation peaks with half wave potentials of 0.70 V and 0.98 V vs. Ag/AgCl, respectively, and they have low optical band gaps (1.88 eV for P1 and 1.72 eV for P2). It is also noted that the polymers exhibit multielectrochromic properties upon doping: P1 can be switched from pink color in the neutral state to blue color in the oxidized state and P2 can be switched from transmissive pink color when neutralized to transmissive blue color when oxidized. (C) 2013 Elsevier Ltd. All rights reserved.</description>
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