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HIGH THERMAL STABILITY OF THE OFF-CENTER PARAMAGNETIC Fe3+ IONS IN CHLORINATED SrCl2:Fe2+ CRYSTALS

Ghica, D.; Nistor, S. V.


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/16899</identifier>
  <creators>
    <creator>
      <creatorName>Ghica, D.</creatorName>
      <givenName>D.</givenName>
      <familyName>Ghica</familyName>
      <affiliation>Natl Inst Mat Phys, RO-077125 Bucharest, Romania</affiliation>
    </creator>
    <creator>
      <creatorName>Nistor, S. V.</creatorName>
      <givenName>S. V.</givenName>
      <familyName>Nistor</familyName>
      <affiliation>Natl Inst Mat Phys, RO-077125 Bucharest, Romania</affiliation>
    </creator>
  </creators>
  <titles>
    <title>High Thermal Stability Of The Off-Center Paramagnetic Fe3+ Ions In Chlorinated Srcl2:Fe2+ Crystals</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/16899</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.81043/aperta.16898</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.81043/aperta.16899</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The thermal stability above 300 K of the hole-trapped Fe3+ centers, formed by X-ray irradiation at 80 K in chlorinated SrCl2:Fe2+ crystals, has been investigated by Electron Paramagnetic Resonance. In the temperature range of 300 - 520 K, the trigonal Fe3+ center completely transforms into the cubic Fe3+ center, which further decays up to 700 K. The formation and transformation of the trigonal Fe3+ center, containing off-center Fe3+ ions, is associated with the presence and thermally activated movement of the interstitial Cl- ions, present in excess in chlorinated SrCl2:Fe2+ crystals.</description>
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